T. Rakitskaya, E. V. Kameneva, T. Kiose, V. Volkova
{"title":"低温二氧化硫氧化的固态成分由天然斜沸石、铜(II)和卤化物离子组成","authors":"T. Rakitskaya, E. V. Kameneva, T. Kiose, V. Volkova","doi":"10.1109/OMEE.2014.6912424","DOIUrl":null,"url":null,"abstract":"Solid-state compositions containing copper(II) chloride, halide ions (X<sup>-</sup>), and natural clinoptilolite (N-CLI) were obtained. N-CLI and CuCl<sub>2</sub>-KX/N-CLI samples were characterized by X-ray diffraction phase analysis, IR spectroscopy, thermogravimetry, water vapor adsorption, and pH-metry. In addition, they were tested in the reaction of sulfur dioxide oxidation with air oxygen. As found, N-CLI has no protective properties against sulfur dioxide and the protective time of CuCl<sub>2</sub>-KX/N-CLI increases in the order Cl<sup>-</sup> <; Br<sup>-</sup> <; I<sup>-</sup>.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"53 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Solid-state compositions for low-temperature sulphur dioxide oxidation consisting of natural clinoptilolite, copper(II) and halide ions\",\"authors\":\"T. Rakitskaya, E. V. Kameneva, T. Kiose, V. Volkova\",\"doi\":\"10.1109/OMEE.2014.6912424\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Solid-state compositions containing copper(II) chloride, halide ions (X<sup>-</sup>), and natural clinoptilolite (N-CLI) were obtained. N-CLI and CuCl<sub>2</sub>-KX/N-CLI samples were characterized by X-ray diffraction phase analysis, IR spectroscopy, thermogravimetry, water vapor adsorption, and pH-metry. In addition, they were tested in the reaction of sulfur dioxide oxidation with air oxygen. As found, N-CLI has no protective properties against sulfur dioxide and the protective time of CuCl<sub>2</sub>-KX/N-CLI increases in the order Cl<sup>-</sup> <; Br<sup>-</sup> <; I<sup>-</sup>.\",\"PeriodicalId\":142377,\"journal\":{\"name\":\"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)\",\"volume\":\"53 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2014-05-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/OMEE.2014.6912424\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/OMEE.2014.6912424","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Solid-state compositions for low-temperature sulphur dioxide oxidation consisting of natural clinoptilolite, copper(II) and halide ions
Solid-state compositions containing copper(II) chloride, halide ions (X-), and natural clinoptilolite (N-CLI) were obtained. N-CLI and CuCl2-KX/N-CLI samples were characterized by X-ray diffraction phase analysis, IR spectroscopy, thermogravimetry, water vapor adsorption, and pH-metry. In addition, they were tested in the reaction of sulfur dioxide oxidation with air oxygen. As found, N-CLI has no protective properties against sulfur dioxide and the protective time of CuCl2-KX/N-CLI increases in the order Cl- <; Br- <; I-.
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