锂离子电池负极仿生三维非晶碳膜的制备及力学性能研究

Xueliang Wang, Z. Qu, Yaping Wang
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引用次数: 0

摘要

以水果废柚皮为原料,制备了具有连续碳骨架的三维非晶碳基膜材料。在纵向上,碳膜的内表面呈现出独特的结构,即带有碳阶梯的可卷曲梯子紧密地围绕着垂直的弦条,这被认为有助于提高碳膜的机械强度。拉伸试验表明,薄膜材料的屈服阶段延长,相应的断裂形貌呈现不同的断裂面,证实了改变裂纹方向对外加载荷的缓解作用。此外,碳膜材料的弹性模量为140 MPa。碳膜材料作为锂离子电池负极材料,其屈服期的延长有利于其结构的稳定性。
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Fabrication and Mechanical Property of Bioinspired Three Dimensional Amorphous Carbon Membrane As Anode in Lithium Ion Battery
3D amorphous carbon-based membrane materials with continuous carbon skeleton were obtained from the fruit waste pomelo peel. The microstructure shows honeycomb in the transverse direction with pore size ranging from 50∼100 μm, while in the longitudinal direction, the inner surface of the carbon membrane shows unique structure, i.e., rollable ladders with carbon rungs twinkled intimately around the vertical stringers, which is considered to contribute to the mechanical strength of the carbon membrane. The tensile test indicates that prolonged yield stage is observed in the stress-strain curve of the membrane material, the corresponding fracture morphology showing different fracture surfaces, which confirms the alleviation of the applied load by changing the crack direction. In addition, the elastic modulus of the carbon membrane material is 140 MPa. The elongation of the yield period is considered to facilitate the structure stability of the carbon membrane material as anode material in Lithium-ion battery (LIBs).
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