用于苯酚分析的氧化石墨烯工作电极的生产伏安法

P. Setiarso
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引用次数: 0

摘要

伏安法中的工作电极是对氧化还原反应中产生的电流作出响应的电极。工作电极通过迁移、对流和扩散的过程来响应电流。可根据需要制作工作电极,进行定性和定量分析。制备了氧化石墨烯作为工作电极,用锤击法制备了氧化石墨烯作为苯酚传感器样品。利用红外光谱(IR)、x射线衍射(XRD)、扫描电镜(SEM)对氧化石墨烯工作电极进行了表征。铜线电缆作为电极体,长15厘米,直径2mm,填充0.001mg氧化石墨烯,然后压实至光滑。与HPLC相比,氧化石墨烯电极已被用于伏安法测量苯酚。采用伏安法和高效液相色谱法测定10 ppm苯酚样品的回收率分别为97.4%和97.6%。关键词:伏安法;氧化石墨;苯酚
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Production Of Working Electrodes Graphene Oxide For Phenol Analysis Voltammetrically
The working electrode in the voltammetry method is an electrode that responds to the current generated in a redox reaction. The working Electrode to response currents through the process of migration, convection and diffusion. Working electrodes can be made according to the needs for qualitative and quantitative analysis. Graphen oxide as working electrodes have been made, as phenol sensor samples, graphen oxide has been made by hammer methods. Graphen oxide working electrodes are characterized using IR, XRD, SEM. The copper wire cable as electrode body is made a 15 cm long 2mm diameter filled with 0.001mg graphen oxide which is then compacted until smooth. Graphene oxide electrodes have been used for the measurement of phenol by voltammetry compared to HPLC. Measurements applied to the concentration of 10 ppm phenol samples obtained by voltammetry recovery were obtained 97.4% and HPLC obtained 97.6%. Keywords—voltammetry, graphen oxide, phenol
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