Cr/Cu/Ni碰撞下金属化研究

Tay Hui Leng, Galen Kirkpatrick, A. Tay, Lu Li
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引用次数: 2

摘要

在使用共晶铅锡凸点的倒装芯片互连中,需要高度可靠的凸点下金属化(UBM)来保持附着力和焊料润湿性。实验研究了Cr/Cu/Ni ubm的热稳定性,其中Cr作为粘合剂,Cu作为焊料可湿性层,Ni作为屏障。良好热稳定性的工艺窗口将减少硅坑失效和金属间失效,确保可靠性。采用低、中、高三种不同厚度的Cu和Ni层,研究其对钎料凸点强度的影响及失效机理。5/spl倍/ 3mm全阵列测试芯片(含Cr/Cu/Ni UBM)进行了热稳定性测试(1)多次回流1倍、5倍、10倍、20倍和(2)在150/spl℃的高温下储存1000小时。进行了破坏球剪试验和截面分析。碰撞剪切结果表明,随Ni厚度从低到高,Cr/Cu/Ni复合材料随回流循环次数的增加保持稳定。失效是内聚的(模式i -在焊料内)。较高的Ni厚度抑制了Cu的扩散,抑制了Cu在钎料界面附近的IMC形成。在高温贮藏下,金属间化合物的生长加速,形成的过量金属间化合物非常脆。对于低Ni厚度,时效(>500小时)后出现失效模式(I型+ II型)。在高Ni厚度的UBM中,失效模式仍然是内聚的。对于低至高厚度的Cu微凸点,在多次回流过程中保持剪切强度,并且剪切断口仍保留在焊料内。在Cr/低厚度Cu/中厚度Ni UBM中,当Cu供应有限导致焊料脱湿时,失效模式由t=0时的I型失效转变为时效后的III型界面失效。
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Cr/Cu/Ni underbump metallization study
In flip chip interconnection using eutectic Pb/Sn solder bumps, a highly reliable underbump metallization (UBM) is required to maintain adhesion and solder wettability. An experimental study investigated the thermal stability of the Cr/Cu/Ni UBM-where Cr act as an adhesive, Cu a solder wettable layer and Ni a barrier. The process window for good thermal stability will reduce silicon cratering failure and intermetallic failure to ensure reliability. The Cu and Ni layers were varied in low, medium and high thickness to study their impact on solder bump strength and failure mechanisms. 5/spl times/3 mm full array test chips (with Cr/Cu/Ni UBM) were subjected to thermal stability tests (1) multiple reflow for 1x, 5x, 10x, 20x and (2) high temperature storage at 150/spl deg/C up to 1000 hrs. Destructive ball shear test and cross-sectional analysis was done. Bump shear results show that the Cr/Cu/Ni UBM, with Ni thickness (low to high) remains stable with respect to the number of reflow cycles. The failures were cohesive (Mode I-within solder). A high Ni thickness inhibited Cu diffusion and suppressed Cu IMC formation at near solder interface. Under high temperature storage, intermetallic growth was accelerated and the excessive intermetallic formed was very brittle. For low Ni thickness, failure mode (Mode I+ Mode II) was observed after aging (>500 hrs). Failure mode remained as cohesive in high Ni thickness UBM. For low to high thickness Cu mini-bumps, shear strength was maintained during multiple reflows and the shearing fracture remains within the solder. Failure mode shifted from Mode I (at t=0) to Mode III interfacial failure (after aging) in Cr/low thickness Cu/medium thickness Ni UBM, when the limited Cu supply led to solder dewetting.
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