从锂离子电池正极材料Ni0.8 Mn0.1 Co0.1废镍催化剂中萃取高纯镍

Rizqia Afifatu Latifah, S. S. Nisa, A. Jumari, C. Yudha, H. Widiyandari
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引用次数: 0

摘要

由于被认为是环保的便携式设备和电动汽车的大量出现,锂离子电池的使用也在增加。阴极是锂离子电池中对离子输送起重要作用的电极之一。富镍镍锰钴(NMC)是最常用的阴极之一。对锂离子电池日益增长的需求也导致镍作为正极材料的使用增加,因此需要其他来源的镍。利用从废镍催化剂中回收的镍可以作为镍的替代来源的一种解决方案。废镍催化剂属于危险有毒废物之一,采用该回收工艺可以减少催化剂废物的数量。用酸浸法从废镍催化剂中提取镍。所使用的酸为2M的不同料液比的乳酸。废镍催化剂在80℃下浸出3小时。同时,采用草酸为沉淀剂的共沉淀法合成nmc811材料。根据所得结果,产生最高浸出效率的比例变化为20 g /L。得到的NMC材料在两个θ 15-20°和40-46°处有高峰。nmc811材料的形貌为球状,形状均匀,尺寸不均匀。通过对电池进行充放电测试,获得的电池容量达到119毫安时。
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Extraction of High Purely Nickel from Spent Nickel Catalyst for Cathode Material Lithium-Ion Batteries Ni0.8 Mn0.1 Co0.1
The use of lithium-ion batteries has increased due to the large number of portable devices and electric vehicles that are considered environmentally friendly. The cathode is one of the electrodes that have an important role in ion delivery in lithium-ion batteries. Ni-rich Nickel Manganese Cobalt (NMC) is one of the most frequently used cathodes. The increasing demand for lithium-ion batteries has also led to an increase in the use of nickel as a cathode material, so that other sources of nickel are needed. The use of nickel recovered from a spent nickel catalyst can be a solution for alternative sources of nickel. Spent nickel catalyst is one of the hazardous and toxic wastes, so this recovery process can reduce the amount of catalyst waste. Nickel is extracted from a spent nickel catalyst using the acid leaching method. The acid used is 2M lactic acid with various solid/liquid ratios. Spent nickel catalyst leaching was carried out at 80°C for3 hours. At the same time, the synthesis of NMC 811 material used the co-precipitation method with oxalic acid as the precipitant. Based on the results obtained, the variation of the ratio that produces the highest leaching efficiency is 20 grams/L. The obtained NMC material has high peaks at two theta 15-20° and 40-46°. The morphology of the NMC 811 material is agglomerated with a homogeneous shape and inhomogeneous size. Based on the charge discharge test on the battery, the battery capacity obtained reached 119 mAh.
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