Huang Chen, Xiuyu Shi, Jin Wang, Yang Hu, Qian Wang, Jian Cai
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To achieve void free hybrid bonding interface, efforts were mainly paid to some key aspects. Surface pre-treatment were firstly introduced to ensure no oxidation and residual polymer on the surface of bumps before bonding. A combination of plasma and formic gas treatment were adopted. Furthermore, considering coefficients of thermal expansion (CTE) mismatch of BCB and embedded bumps, a compatible bonding process with well-matched temperature and stress was proposed and optimized to get a void-free bonding interface under the guidance of independent variable test result. Bonding interface microstructure was observed and mechanical test, electrical test of Kelvin and daisy-chain structure were performed to evaluate bonding quality, also reliability test which included HTST and TCT had been carried out. 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Furthermore, considering coefficients of thermal expansion (CTE) mismatch of BCB and embedded bumps, a compatible bonding process with well-matched temperature and stress was proposed and optimized to get a void-free bonding interface under the guidance of independent variable test result. Bonding interface microstructure was observed and mechanical test, electrical test of Kelvin and daisy-chain structure were performed to evaluate bonding quality, also reliability test which included HTST and TCT had been carried out. 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引用次数: 2
摘要
高密度、细间距晶圆级键合技术是实现异质集成的必要条件。然而,当粘接间距减小时,下填料将是一个挑战。同时采用金属-金属和钝化-钝化键合的杂化键合技术是可行的解决方案。本文研究了不对称嵌入Cu- sn /Cu凸点结构的杂化键合方案。作为钝化材料的光敏BCB仅涂覆在键对的一侧。这种非对称结构允许精确对准。在250℃的温度下,实现了BCB固化和Cu-Sn固-液-扩散键合。考虑到聚合物在粘接过程中的体积收缩,对BCB和金属的厚度进行了简明的设计。为实现无空隙杂化键合界面,重点从几个关键方面进行了研究。首先介绍了表面预处理,以确保在粘合前凸点表面无氧化和残留聚合物。采用等离子体和甲醛气相结合的处理方法。在自变量试验结果的指导下,考虑BCB热膨胀系数(CTE)与嵌入凸点的失配,提出并优化了温度与应力匹配良好的兼容键合工艺,得到无空洞的键合界面。观察粘接界面微观结构,进行力学试验、Kelvin试验和菊链结构电学试验评价粘接质量,并进行HTST和TCT可靠性试验。结果证实,嵌入式凹凸混合键合将是未来3D集成的一种令人信服的技术。
Development of Hybrid Bonding Process for Embedded Bump with Cu-Sn/BCB Structure
High density, fine pitch wafer level bonding technology is necessary for heterogeneous integration. However, underfill would be a challenging when bonding pitch decreases. Hybrid bonding technology with metal-to-metal and passivation-to-passivation bonding simultaneously was considered as a feasible solution. In this work, a hybrid bonding scheme with asymmetric embedded Cu-Sn/Cu bumps structure was investigated. Photosensitive BCB used as passivation materials was coated on only one side of bonding pairs. This asymmetric structure allows for precise alignment. BCB curing and Cu-Sn Solid-liquid-diffusion bonding were both achieved under the temperature of 250°C. The thickness of BCB and metal was concisely designed considering the volume shrinking of polymer during bonding process. To achieve void free hybrid bonding interface, efforts were mainly paid to some key aspects. Surface pre-treatment were firstly introduced to ensure no oxidation and residual polymer on the surface of bumps before bonding. A combination of plasma and formic gas treatment were adopted. Furthermore, considering coefficients of thermal expansion (CTE) mismatch of BCB and embedded bumps, a compatible bonding process with well-matched temperature and stress was proposed and optimized to get a void-free bonding interface under the guidance of independent variable test result. Bonding interface microstructure was observed and mechanical test, electrical test of Kelvin and daisy-chain structure were performed to evaluate bonding quality, also reliability test which included HTST and TCT had been carried out. The results confirmed that embedded bump hybrid bonding would be a convincing technology for future 3D integration.