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引用次数: 0

摘要

采用TSDC(热刺激去极化电流)方法研究了聚合物结构对聚苯基喹啉电学性能的影响。在TSDC谱中可分辨出7个弛豫区。观察到这些区域的概率很大程度上取决于样品的退火程度。PETP中的TSDC也受到物理结构的影响。研究了纯聚甲基丙烯酸甲酯和皂化聚甲基丙烯酸甲酯的TSDC光谱。观察到三个弛豫区:-弛豫区和-弛豫区以及空间电荷弛豫区。
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The influence of the polymer structure on the electrical properties
The TSDC (thermally stimulated depolarization current) method was used to study the effect of polymer structure on electrical properties for poly(phenylquinooxaline). Seven relaxation regions were distinguished in the TSDC spectrum. The probability of observing the regions depends strongly on the degree of annealing of the samples. The TSDC in PETP is also found to be influenced by the physical structure. The TSDC spectrum of pure and saponificated poly(methylmethacrylate) was investigated. Three relaxation regions were observed: the beta - and alpha -relaxation and a space charge relaxation.<>
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