BiScO3-BaTiO3-(K1/2Bi1/2)TiO3三元体系的介电行为

J. B. Lim, S. Zhang, N. Kim, T. Shrout
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引用次数: 1

摘要

研究了钙钛矿固溶体体系中(1¿x)[0.4BiScO3¿0.6BaTiO3] + x (K1/2Bi1/2)TiO3 [BSBT-KBTx]陶瓷在高温电容器中的潜在应用。研究了BSBT-KBTx陶瓷的介电性能随温度和频率的变化规律。BSBT-KBTx陶瓷在100 ~ 300℃范围内具有较高的介电常数(> 1000 @RT)和较低的介电损耗,温度系数(TCC)较平坦。此外,BSBT-KBTx陶瓷在温度> 300 K时具有介电弛豫,极化测量结果显示,在120 kV/cm时,BSBT-KBTx陶瓷具有1.8 J/cm3的高储能密度。因此,这种新型三元体系中的介电材料似乎是高温和储能电容器的有希望的候选者。
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Dielectric behavior in the BiScO3-BaTiO3-(K1/2Bi1/2)TiO3 ternary system
(1¿x)[0.4BiScO3¿0.6BaTiO3] + x (K1/2Bi1/2)TiO3 [BSBT-KBTx] ceramics in the perovskite solid solution system were studied for potential high temperature capacitor applications. The diectric properties of BSBT-KBTx ceramics were investigated as a function temperature and frequency. The BSBT-KBTx ceramics showed high dielectric permittivity (> 1000 @RT) and low dielectric loss over the temperature range from 100 ~ 300°C with a flat temperature coefficient (TCC). In addition, BSBT-KBTx ceramics were observed to possess a dielectric relaxation at temperatures (> 300 K). Polarization measurements as a function of electric field showed high energy storage densities with 1.8 J/cm3 at 120 kV/cm. Therefore, dielectrics in this novel ternary system appear to be promising candidates for high temperature and energy storage capacitors.
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