大重量可逆反乳化钻井液的实验室研究

L. Fei, Yanling Wang, Kun Wang, J. Ren, Yue Zhang, A. Asteria, Zichen Yin
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引用次数: 0

摘要

基于胺的质子化可逆性,发明了一种新型可逆反乳化钻井液,有助于解决钻井效率、固井和环境效应之间的矛盾。新型钻井液具有可逆的乳状相特性。可逆反乳化钻井液的配方为:白油(5)+25%氯化钙卤水+50%增重剂ZFU-3+1.5%有机粘土+0.5%石灰+4.5%可逆乳化剂UPSG-1+1%润湿剂DYSL-3+适量重晶石,油液与非油液比为50/50,钻井液密度为1.9 kg/L,增重剂ZFU为甲酸钠。综合性能评价和实验室测试表明,新型钻井液可以通过酸基化学开关,轻松、可逆地从油包水乳化液转化为油包水乳化液,再转化为油包水乳化液。转化前后乳化泥浆性能良好,破乳电压900 ~ 1100 V,耐高温150℃,HEHP滤失量小于6 ml,滤饼和含油岩屑易于处理。由此可见,可逆反乳化钻井液具有油基钻井液和水基钻井液的双重优点,各项性能优良。可逆反乳化钻井液能够解决常规油基钻井液的应用问题。可逆反乳化钻井液的密度为1.9 kg/L,也优于传统的可逆反乳化钻井液。
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Laboratory Study of the Heavy Weight Reversible Invert Emulsion Drilling Fluid
A novel reversible invert emulsion drilling fluid which is useful in resolving the contradiction between drilling efficiency, cementing and environmental effect has been invented based on the protonation reversibility of amine. The new drilling fluid has reversible emulsion-phase behavior. The formulation of the reversible invert emulsion drilling fluid was: white oil (5)+25% CaCl 2 brine+50% weight agent ZFU-3+1.5% organoclay+0.5% lime +4.5% reversible emulsifier UPSG-1+1% wetting agent DYSL-3+an appropriate amount barite, oleaginous fluid to non-oleaginous fluid-ratio was 50/50, drilling fluid density was 1.9 kg/L, weight agent ZFU is sodium formate. Comprehensive performance evaluation with laboratory test showed that the new drilling fluid could be readily and reversibly converted from a water-in-oil emulsion to an oil-in water emulsion and back to a water-in-oil emulsion using an acid-based chemical switch. And before and after converting the emulsion mud maintains good performance, with emulsion-breaking voltage of 900-1,100 V, resistance to temperature of 150℃, HEHP filter loss of less than 6 ml. Additionally, the filter cake and oily cuttings could be treated easily. This suggests that the reversible invert emulsion drilling fluid has both merits of oil-based fluid and water –based fluids, and all properties are excellent. The reversible invert emulsion drilling fluid is capable of resolving the problems with the application of conventional oil-based drilling fluid. The density of the reversible invert emulsion is 1.9 kg/L, which is also better than the traditional reversible invert emulsion drilling fluid.
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