反应代谢多相催化剂制备椰子油生物柴油

A. Awaluddin, Padil, S. Wahyuningsih
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引用次数: 4

摘要

生物柴油是一种可替代能源。生物柴油可以由椰子油制成,被称为椰子柴油。本研究以碳酸钙(CaCO3)为异质催化剂,在900℃下煅烧1.5 h,研究了椰子油与甲醇甲醇解反应生产椰子柴油的最佳条件。通过催化剂浓度1 ~ 3% -wt、甲醇/椰子油摩尔比4∶1 ~ 12∶1等实验参数,确定了最佳工艺条件。实验得到的最佳工艺条件为:催化剂浓度为2%,甲醇与椰子油的摩尔比为8∶1,反应温度为60℃,可使椰子柴油的最高转化率达到75.02%。该椰子柴油符合印尼国家标准(SNI)规范要求,密度为860 kg/m3,运动粘度为2.44 mm2/s,闪点为110℃,含水量为0.039% -v, setana值为65.94,酸值为0.049 mg KOH/g,碘值为6.35 gr iod /100 gr。经数据分析,该产品具有柴油资质。
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Making biodiesel from coconut oil by reaction metanolisis heterogeneous catalyst
Biodiesel is one of alternative energies. Biodiesel can be made from coconut oil and is referred to as cocodiesel. This research studies the optimum condition of cocodiesel production by methanolysis reaction between coconut oil and methanol using heterogen catalyst of calcium carbonate (CaCO3) is calcined for 1.5 hours at 900°C. In order to get optimum condition, several experimental parameters are applied such as catalyst concentration 1–3 %-wt and molar ratio of methanol/coconut oil 4∶1–12∶1. The optimum condition obtained from this experimental as follow: catalyst concentration was 2%, molar ratio of methanol/coconut oil was 8∶1 at 60°C, produced the higgest conversion of cocodiesel 75.02%. The cocodiesel meet the requirement of Standar National Indonesia (SNI) specifications, where the density was 860 kg/m3, kinematic viscosity was 2.44 mm2/s, flash point was 110°C, water content was 0,039%-v, setana number was 65.94, acid number was 0.049 mg KOH/g and iod number was 6.35 gr Iod/100 gr. Based on data analysis, the product has a qualification as diesel fuel.
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