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引用次数: 12

摘要

先前作者(1957,1984)已经证明聚乙烯(PE)的弛豫可以用速率理论很好地描述。结果表明,速率理论适用于低于熔化温度的时效。时效过程在热力学转变的两侧具有不同的能量参数。强调了在适当的温度范围内进行加速老化试验的重要性。
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The compensation law and polymer aging and relaxations
It has been shown previously by the author (1957, 1984) that the relaxation of polyethylene (PE) can be well described by the rate theory. It is shown here that the rate theory applies to aging at temperatures below the melting temperature. It is also shown that the aging process has different energy parameters on the two sides of a thermodynamic transition. The importance of performing accelerated aging tests within the appropriate temperature range is stressed.<>
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