共挤聚丙烯基背板的开裂倾向研究

G. Oreski, C. Barretta, A. Macher, G. Eder, L. Neumaier, M. Feichtner, M. Aarnio-Winterhof
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摘要

基于聚丙烯(PP)的共挤背板是一种有趣的替代层压背板含有聚酯薄膜(PET)。在过去的几年里,背板开裂已经成为一种常见的故障模式,不仅会引起安全问题,而且从长远来看也会降低光伏组件的使用寿命。在这项工作中,研究了三种不同背板的裂纹敏感性,使用焊料凹凸片试样:两种基于聚酰胺(pa)和PP的共挤背板,以及一种含有PET芯层和聚氯乙烯(PVF)外层的层压背板。焊料凹凸片暴露于紫外线下的测试序列,然后进行热循环。总体而言,PP以及PVF-PE T背板表现出优异的稳定性,并且对材料脆化或开裂没有敏感性。相比之下,基于PA的背板在几个测试周期后显示出明显的变色和强烈的开裂。总体而言,该研究证实,共挤PP背板显示出巨大的潜力,可以有效替代光伏组件中基于PET的标准背板。
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Investigation of the crack propensity of co-extruded polypropylene based backsheets
Co-extruded backsheets based on polypropylene (PP) are an interesting alternative to laminated backsheets containing polyester films (PET). Backsheet cracking has become a frequent failure mode in the last years, causing not only safety issues but on the long term also reducing the lifetime of PV modules. In this work the crack susceptibility of three different backsheets was investigated using solder bump coupon specimens: two co-extruded backsheets based on polyamide (P A) and PP, together with one laminated backsheet containing a PET core layer and polyvinyl fluoride (PVF) outer layers. The solder bump coupons were exposed to test sequence of exposure to UV light followed by thermal cycles. Overall, the PP as well as the PVF-PE T backsheet showed excellent stability and no susceptibility to material embrittlement or cracking. By comparison, the PA based backsheets showed next to significant discoloration also strong cracking after a few test cycles. Overall, the study confirms that co-extruded PP backsheets show great potential to be a valid replacement of standard PET based backsheets in PV modules.
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