电沉积混合钙钛矿的性能和稳定性$\text{MAPbI}_{3-\ mathm {x}}\text{Cl}_{\ mathm {x}}$和$\text{MA}_{1-\ mathm {y}}\text{FA}_{\ mathm {y}}\text{PbI}_{3-\ mathm {x}}\text{Br}} {\ mathm {x}}$

Mirella Al Katrib, L. Perrin, E. Planès
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引用次数: 0

摘要

本文研究了电沉积法制备大面积钙钛矿活性层的替代方法。除了简单的MAPbI3钙钛矿外,还研究了混合钙钛矿$\text{MAPbI}_{3-\ mathm {x}}\text{Cl}_{\ mathm {x}}$和$\text{MA}_{1-} {{\ mathm {y}}\text{FA} {\ mathm {y}}\text{PbI}_{3-\ mathm {x}}\text{Br} {\ mathm {x}}$的沉积。目前的研究是此类研究中的一个,因为这些混合钙钛矿以前从未使用电沉积方法开发过。研究发现,在太阳能器件中使用这些混合钙钛矿可以增强其光伏活性。当在轻度老化条件下(40°C,真空或环境气氛下)500h评估时,它也增强了其稳定性。采用电沉积法制备的不同钙钛矿均经历成熟现象。
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Performance and stability of electrodeposited mixed perovskites $\text{MAPbI}_{3-\mathrm{x}}\text{Cl}_{\mathrm{x}}$ and $\text{MA}_{1-\mathrm{y}}\text{FA}_{\mathrm{y}}\text{PbI}_{3-\mathrm{x}}\text{Br}_{\mathrm{x}}$
Electrodeposition was investigated in this work as a substitute method to develop large area perovskite active layer for solar device application. Along with the simple MAPbI3 perovskite, the deposition of mixed $\text{MAPbI}_{3-\mathrm{x}}\text{Cl}_{\mathrm{x}}$ and $\text{MA}_{1-} {}_{\mathrm{y}}\text{FA}_{\mathrm{y}}\text{PbI}_{3-\mathrm{x}}\text{Br}_{\mathrm{x}}$ perovskites was studied. This present study is one of its kind, since these mixed perovskite were never developed using electrodeposition before. It was detected that using these mixed perovskites in a solar device enhances its photovoltaic activity. It also enhances its stability when evaluated in mild ageing conditions (40°C, under vacuum or ambient atmosphere) during 500h. The different perovskites fabricated using electrodeposition experience a maturation phenomenon.
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