{"title":"EuCoO3-EuFeO3体系的结构行为","authors":"O. Pekinchak, L. Vasylechko, Y. Prots","doi":"10.1109/OMEE.2014.6912331","DOIUrl":null,"url":null,"abstract":"The work deals with the study of the phase and structural behaviour of mixed europium cobaltites-ferrites formed in the EuCoO<sub>3</sub>-EuFeO<sub>3</sub> pseudo-binary system. Formation of a continuous solid solution EuCo<sub>1-x</sub>Fe<sub>x</sub>O<sub>3</sub> with orthorhombic perovskite structure (GdFeO<sub>3</sub> type, space group Pbnm) has been revealed. Crystal structure parameters of the mixed europium cobaltites-ferrites have been established by the full profile Rietveld refinement. Based on the analysis of structural parameters, an influence of the cation substitution on the deformation of the orthorhombic perovskite structure in the EuCo<sub>1-x</sub>Fe<sub>x</sub>O<sub>3</sub> series has been established.","PeriodicalId":142377,"journal":{"name":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","volume":"52 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2014-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Structural behavior in the EuCoO3-EuFeO3 System\",\"authors\":\"O. Pekinchak, L. Vasylechko, Y. Prots\",\"doi\":\"10.1109/OMEE.2014.6912331\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The work deals with the study of the phase and structural behaviour of mixed europium cobaltites-ferrites formed in the EuCoO<sub>3</sub>-EuFeO<sub>3</sub> pseudo-binary system. Formation of a continuous solid solution EuCo<sub>1-x</sub>Fe<sub>x</sub>O<sub>3</sub> with orthorhombic perovskite structure (GdFeO<sub>3</sub> type, space group Pbnm) has been revealed. Crystal structure parameters of the mixed europium cobaltites-ferrites have been established by the full profile Rietveld refinement. Based on the analysis of structural parameters, an influence of the cation substitution on the deformation of the orthorhombic perovskite structure in the EuCo<sub>1-x</sub>Fe<sub>x</sub>O<sub>3</sub> series has been established.\",\"PeriodicalId\":142377,\"journal\":{\"name\":\"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)\",\"volume\":\"52 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2014-05-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/OMEE.2014.6912331\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/OMEE.2014.6912331","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The work deals with the study of the phase and structural behaviour of mixed europium cobaltites-ferrites formed in the EuCoO3-EuFeO3 pseudo-binary system. Formation of a continuous solid solution EuCo1-xFexO3 with orthorhombic perovskite structure (GdFeO3 type, space group Pbnm) has been revealed. Crystal structure parameters of the mixed europium cobaltites-ferrites have been established by the full profile Rietveld refinement. Based on the analysis of structural parameters, an influence of the cation substitution on the deformation of the orthorhombic perovskite structure in the EuCo1-xFexO3 series has been established.