MoO3孔注入塑料箔柔性聚合物整流二极管

Miao Li, Nazmul Rafi, Paul R. Berger, D. Lupo, M. Mantysalo
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引用次数: 0

摘要

本文研制了一种铝/吲哚二噻吩-苯并噻唑(C16-IDT-BT)/三氧化钼/金结构的柔性溶液加工聚合物二极管。在2 V电压下,直流整流比为7×103,正向电流密度为2.6 mA/cm2,反向电流密度为0.37µA/cm2。uv -臭氧处理的MoO3层作为C16-IDT-BT层的注孔层,增强正向电流密度。与银相比,金电极具有更高的功函数,是聚合物二极管的优良阳极。该二极管可用作阻塞二极管,以使电流沿所需方向流动。
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Flexible Polymer Rectifying Diode on Plastic Foils with MoO3 Hole Injection
In this work, a flexible solution processed polymer diode with a structure of aluminum/indacenodithiophene-benzothiadiazole (C16-IDT-BT)/molybdenum trioxide/gold was developed. A DC rectification ratio of 7×103 was achieved at 2 V with a forward current density of 2.6 mA/cm2 and a reverse current density of 0.37 µA/cm2. The UV-ozone treated MoO3 layer acted as a hole injection layer for the C16-IDT-BT layer to enhance the forward current density. The Au electrode with a higher work function compared to Ag was a superior anode for the polymer diode. The diode can be used as a blocking diode to allow the current to flow in the desired direction.
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