吸附气体的表面电导测量

C. Bargeron, T. E. Phillips, R. Benson
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摘要

吸附水、二氧化碳和氨的表面电导已被测量为温度的函数,使用三轨测试衬底。对单个纯气体及其混合物进行了研究。发现吸附的二氧化碳或氨具有可忽略不计的表面电导,而吸附的水在-25/spl度/C开始表现出电导的增加。二氧化碳和水的混合物表现出与水本身基本相同的电导,而氨和水的混合物在-40和0之间表现出比水大10/ 4倍的电导。这三种气体的混合物在较低温度下(-100/spl℃至-50/spl℃)的电导相对较低。相应的压力测量表明,在某些情况下,蒸发被极大地抑制,表明吸附物质之间的相互作用很强。
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Surface conductance measurements of adsorbed gases
The surface conductance of adsorbed water, carbon dioxide, and ammonia has been measured as a function of temperature using a triple-track test substrate. The individual pure gases were studied along with their mixtures. Adsorbed carbon dioxide or ammonia was found to have a negligible surface conductance, while adsorbed water exhibited an increase in conductance beginning at -25/spl deg/C. Mixtures of carbon dioxide and water exhibited essentially the same conductance as water by itself, while mixtures of ammonia and water exhibited a conductance 10/sup 4/ times larger than water between -40/spl deg/C and 0/spl deg/C. Mixtures of all three gases resulted in a relatively low conductance at lower temperatures (-100/spl deg/C to -50/spl deg/C). Corresponding pressure measurements indicated that vaporization was greatly suppressed in some cases, suggesting strong interaction between the adsorbed species.<>
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