含铜钾铝硼酸盐玻璃结构与非线性光学性质的关系

P. Shirshnev, N. Nikonorov, A. Babkina, A. Kim, D. Sobolev, I. Kislyakov, S. Povarov, I. Belousova, E. Kolobkova
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引用次数: 1

摘要

介绍了用氯化铜纳米晶制备硼酸钾铝玻璃的工艺。玻璃在可见光范围内的透射率超过75%,非线性阈值小于10-5焦耳(波长为532 nm)。这种低阈值可以用硼酸钾铝玻璃中含铜纳米相的特殊结构来解释。在PAB玻璃中,纳米相的低温会引起光学非线性效应。在磷酸盐玻璃中,铜离子和铜团簇是造成光学非线性的原因。
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Copper-containing potassium-alumina-borate glass structure and nonlinear optical properties correlation
The paper describes the technology of obtaining potassium-alumina-borate glass with nanocrystalls of copper chloride. Glass has transmission more than 75 % in visible range and nonlinear threshold less than 10-5 Joules (at the wavelength of 532 nm). Such low threshold can be explained by special structure of copper-containing nanophase in potassium-alumina-borate glass. In PAB glass low-melting temperatures of nanophase induce nonlinear effects in optics. In phosphate glass copper ions and clusters are responsible for optical nonlinearity.
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