用纳米压印技术复制灰度抗蚀剂母版的三维图案

Api Warsono, Diana-Stephany Fernandez Rodas, J. Reche, Anaïs De Lehelle D'Affroux, Sébastien Berard Bergery
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摘要

首先,在ea - leti开发的灰度i线光刻工艺允许在众所周知的光刻技术的基础上制造各种3D图案。灰度光刻技术是一种创新的、可替代的方法来创建3D模式,例如微透镜。在不同剂量下曝光低对比度的抗蚀剂会导致抗蚀剂膜的厚度不同。本征剂量的变化是通过使用具有不同铬密度的二元掩模来获得的,从而调节抗蚀剂表面的暴露强度1。其次,纳米压印光刻(NIL)是一种能够再现广泛形态范围的技术。对于3D图案的再现,越来越多地要求使用NIL。最初,标准NIL工艺使用通常由Si或SiO2组成的硬母材。提出的工作验证了纳米压印工艺对灰度光刻产生的“抗蚀母片”的复制质量。这种方法通过避免蚀刻步骤并提供具有成本效益的解决方案,简化了母片的制造过程。在本研究中,在复制前后进行了几种类型3D图案的测量。对32种同时复制的微透镜进行CD保存评价。最后,灰度和纳米压印技术的结合可以大大增加印刷的可能性。通过消除蚀刻过程中多种模式形态保存的困难,抗蚀剂母片的复制允许其他潜在的应用,特别是在光学领域。
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Replication of 3D patterns from a grayscale resist master by nanoimprint process
First, Grayscale I-Line lithography process developed in CEA-Leti allows to manufacture a variety of 3D patterns based on the well-known photolithography technology. Grayscale photolithography is an innovative and alternative approach to create 3D patterns such as microlenses for example. Exposure of a low contrast resist at different doses results in different thicknesses in the resist film. The variation of the intrinsic dose is obtained by using a binary mask that has different chromium densities, thus modulating the exposure intensity on the resist surface1. Secondly, the NanoImprint Lithography (NIL) is a technology capable of reproducing a wide morphological range. NIL is increasingly requested for the reproduction of 3D patterns. Initially, standard NIL process uses a hard master usually composed of Si or SiO2. The proposed work validates the quality of the replication by the NanoImprint process of a "resist master" created by grayscale lithography. This approach facilitates the manufacturing process of a master by avoiding the etching step and offering a cost-effective solution. The measurement of several types of 3D patterns are performed before and after replication during this study. CD preservation is evaluated for 32 types of microlenses simultaneously replicated. Finally, the combination of the Grayscale and NanoImprint technologies allows to considerably increasing the printing possibilities. By freeing the difficulties of multiple patterns morphology conservation during the etching, the replication of a resist master permits other potential applications, particularly in the optical field.
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