干燥工艺对二氧化硅载体双峰介孔结构理化性质的影响

C. Niamnuy, Noppadol Panchan, Thanaphat Chukeaw, A. Seubsai, S. Devahastin, M. Chareonpanich
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引用次数: 0

摘要

干燥过程直接影响催化剂载体二氧化硅的结构。因此,我们采用溶胶-凝胶法制备了双峰型介孔-大孔结构的二氧化硅,并通过BET和BJH n2吸附以及SEM对热风干燥(HA)、微波干燥(MW)和冷冻干燥(FD)等不同干燥技术得到的二氧化硅载体进行了研究。结果表明,干燥技术对干燥后的双峰多孔二氧化硅载体的结构性能有显著影响。此外,冻干可以提高二氧化硅载体的表面积,高于500 m2/g。关键词:双峰介孔-大孔结构二氧化硅支架;干燥技术;冷冻干燥
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Influence of drying technique on physicochemical properties of bimodal meso-macropore structure of silica support
Drying process directly affect in structure of the silica support for catalysts. Therefore, we herein prepared bimodal meso-macropore structure of silica by sol-gel method and investigated the silica support obtained from various drying techniques, namely, hot air drying (HA), microwave drying(MW)and freeze drying (FD)by means of BET and BJH N2-sorption, and SEM. The results showed a significant effect of drying technique on the textural properties of the dried bimodal porous silica support. In addition, it was found that freeze drying could enhance surface area of silica support with higher than 500 m2/g. Keywords: bimodal meso-macropore structure silica support: drying technology: freeze drying: hot air drying: microwave drying
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