聚合物和金属氧化物空穴传输材料对FASnI3钙钛矿太阳能电池稳定性的影响

B. U, Bidisha Nath, Nagahanumaiah, Praveen C Ramamurthy
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摘要

锡基钙钛矿在无毒太阳能电池应用的发展中是一种令人鼓舞的材料,但其性能受到抗氧和抗湿性差的化学稳定性的限制。因此,锡基钙钛矿太阳能电池大多采用倒平面器件结构制造,其下空穴输运材料的选择对器件的稳定性起着重要的作用。在这项工作中,我们报道了金属氧化物、氧化镍和聚合物聚(3,4-乙烯二氧噻吩):聚苯乙烯磺酸盐(PEDOT: PSS)作为空穴传输层对锡基PSC器件效率和稳定性的比较研究。我们用NiOx获得了相对较高的功率转换效率(PCE),然而,PEDOT: PSS的太阳能电池在没有封装的情况下在氮气环境中持续900小时的时间比NiOx更稳定。
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Comparison of polymeric and metal oxide hole transport material on the stability of FASnI3 perovskite solar cell
The Tin-based perovskite is an encouraging material in the development of non-toxic solar cell application, but its performance is limited by the poor chemical stability against oxygen and moisture. Therefore, tin-based perovskite solar cells are mostly fabricated in inverted planar device structures and the selection of underlying hole transport material plays a significant role in device stability. In this work, we report the comparison study between a metal oxide, nickel oxide, and polymeric poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT: PSS) as a hole transport layer on device efficiency and stability of tin-based PSC. We obtained comparatively higher power conversion efficiency (PCE) with NiOx than others, however, the solar cell with PEDOT: PSS is more stable rather than NiOx for the duration of 900 hrs in a nitrogen ambient, without encapsulation.
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