棕榈叶生物吸附材料在阿莫西林吸附中的应用

IF 1.3 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Cellulose Chemistry and Technology Pub Date : 2023-09-29 DOI:10.35812/cellulosechemtechnol.2023.57.79
KHEIRA DJELLOULI DELLA, GHANIA HENINI, YAKHLEF LAIDANI
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引用次数: 0

摘要

在这项研究中,从棕树叶(BEF)中提取的纤维已经成功地用作一种廉价、可持续和环保的生物吸附剂,通过批处理法从水溶液中去除抗生素阿莫西林(AMX)。该药品存在于生活和工业废水中。利用x射线衍射(XRD)、扫描电镜(SEM)和傅里叶变换红外光谱(FTIR)对BEF进行了表征。XRD结果表明,BEF为半晶结构。SEM图像显示了其形貌、表面结构和多孔性。FTIR结果显示,产物中存在不同的官能团(羟基、羧基、胺等)。分析了孔隙度、灰分、含水率和等电子点(pHpzc)等理化参数。用紫外可见分光光度计(λ = 228 nm)对BEF对阿莫西林的间歇吸附过程进行了监测。研究了不同的操作参数,如接触时间、生物吸附剂质量、pH、温度和吸附质浓度,以找到最大的生物吸附水平。在pH为6.5时,接触时间为90 min,初始阿莫西林浓度为50 mg/L,生物吸附剂质量为1.5 g,温度为313 K,可达到58%的AMX去除率。高温下的最大吸附量表明该生物吸附过程是自发的、吸热的。
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A BIOSORBENT MATERIAL FROM BRAHEA EDULIS PALM LEAVES – APPLICATION TO AMOXICILLIN ADSORPTION
In this study, fibers from the leaves of Brahea edulis palm (BEF) have been successfully used as a cheap, sustainable and eco-friendly biosorbent to remove the antibiotic Amoxicillin (AMX) from an aqueous solution using a batch process. This pharmaceutical product is present in domestic and industrial waste water. The characterization of BEF was carried out by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier Transform infrared spectroscopy (FTIR). The results of XRD showed that BEF has a semicrystalline structure. SEM images revealed its morphology, surface structure and porous nature. FTIR results showed the presence of different functional groups (hydroxyls, carboxyls, amines, etc.). Several physicochemical parameters, such as porosity, ash content, moisture content, and isoelectronic point (pHpzc), were analyzed. The batch biosorption process of Amoxicillin by BEF was monitored with a UV-visible spectrophotometer at λ = 228 nm. Different operating parameters, such as contact time, biosorbent mass, pH, temperature and adsorbate concentration, were evaluated to find the maximum level of biosorption. The contact time of 90 minutes, 50 mg/L initial Amoxicillin concentration, 1.5 g biosorbent mass and 313 K temperature were found to be the optimum conditions that led to a percentage removal of AMX of 58% at pH 6.5. The maximum adsorption at high temperature indicates that this biosorption process is spontaneous and endothermic.
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来源期刊
Cellulose Chemistry and Technology
Cellulose Chemistry and Technology 工程技术-材料科学:纸与木材
CiteScore
2.30
自引率
23.10%
发文量
81
审稿时长
7.3 months
期刊介绍: Cellulose Chemistry and Technology covers the study and exploitation of the industrial applications of carbohydrate polymers in areas such as food, textiles, paper, wood, adhesives, pharmaceuticals, oil field applications and industrial chemistry. Topics include: • studies of structure and properties • biological and industrial development • analytical methods • chemical and microbiological modifications • interactions with other materials
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