高价碘试剂光催化脱羧对羧酸的发散转化

IF 0.2 4区 化学 Q4 CHEMISTRY, ORGANIC Journal of Synthetic Organic Chemistry Japan Pub Date : 2023-11-01 DOI:10.5059/yukigoseikyokaishi.81.1050
Yota Sakakibara, Kenichiro Itami, Kei Murakami
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引用次数: 0

摘要

羧酸是各种原料中最重要的官能团之一。它们的意义在于它们作为有机合成过程中选择性转化的关键中间体的关键作用。尽管存在各种脱羧转化反应,如Kolbe二聚化,但这些方法仍然存在一定的局限性,这为进一步改进提供了机会。在这篇文章中,我们介绍了我们最近在光催化脱羧转化应用方面的研究,该转化允许羧酸的发散转化。
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Divergent Transformation of Carboxylic Acids through Photocatalytic Decarboxylation with Hypervalent Iodine Reagents
Carboxylic acids are one of the most important functional groups found in various feedstocks. Their significance lies in their pivotal role as key intermediates in selective transformations during organic synthesis. Despite the existence of various decarboxylative transformation reactions such as Kolbe dimerization, these methods still exhibit certain limitations that present opportunities for further improvement. In this account, we present our recent studies on the application of photocatalytic decarboxylative transformation that allows the divergent transformation of carboxylic acids.
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来源期刊
CiteScore
0.30
自引率
0.00%
发文量
120
审稿时长
6-12 weeks
期刊介绍: Information not localized
期刊最新文献
Synthetic Element Chemistry based on Precise Designs of Reagents and Transition States Use of Emerging C-H Functionalization Methods to Implement Strategies for the Divergent Total Syntheses of Bridged Polycyclic Natural Products Rapid Alternating Polarity as a Unique Tool for Synthetic Electrochemistry Synthesis of Structurally Diverse Polycyclic Arenes Using Tandem Oxidative Ring Expansion Strategy Divergent Transformation of Carboxylic Acids through Photocatalytic Decarboxylation with Hypervalent Iodine Reagents
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