{"title":"高价碘试剂光催化脱羧对羧酸的发散转化","authors":"Yota Sakakibara, Kenichiro Itami, Kei Murakami","doi":"10.5059/yukigoseikyokaishi.81.1050","DOIUrl":null,"url":null,"abstract":"Carboxylic acids are one of the most important functional groups found in various feedstocks. Their significance lies in their pivotal role as key intermediates in selective transformations during organic synthesis. Despite the existence of various decarboxylative transformation reactions such as Kolbe dimerization, these methods still exhibit certain limitations that present opportunities for further improvement. In this account, we present our recent studies on the application of photocatalytic decarboxylative transformation that allows the divergent transformation of carboxylic acids.","PeriodicalId":17123,"journal":{"name":"Journal of Synthetic Organic Chemistry Japan","volume":"119 5","pages":"0"},"PeriodicalIF":0.2000,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Divergent Transformation of Carboxylic Acids through Photocatalytic Decarboxylation with Hypervalent Iodine Reagents\",\"authors\":\"Yota Sakakibara, Kenichiro Itami, Kei Murakami\",\"doi\":\"10.5059/yukigoseikyokaishi.81.1050\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Carboxylic acids are one of the most important functional groups found in various feedstocks. Their significance lies in their pivotal role as key intermediates in selective transformations during organic synthesis. Despite the existence of various decarboxylative transformation reactions such as Kolbe dimerization, these methods still exhibit certain limitations that present opportunities for further improvement. In this account, we present our recent studies on the application of photocatalytic decarboxylative transformation that allows the divergent transformation of carboxylic acids.\",\"PeriodicalId\":17123,\"journal\":{\"name\":\"Journal of Synthetic Organic Chemistry Japan\",\"volume\":\"119 5\",\"pages\":\"0\"},\"PeriodicalIF\":0.2000,\"publicationDate\":\"2023-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Synthetic Organic Chemistry Japan\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.5059/yukigoseikyokaishi.81.1050\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Synthetic Organic Chemistry Japan","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.5059/yukigoseikyokaishi.81.1050","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Divergent Transformation of Carboxylic Acids through Photocatalytic Decarboxylation with Hypervalent Iodine Reagents
Carboxylic acids are one of the most important functional groups found in various feedstocks. Their significance lies in their pivotal role as key intermediates in selective transformations during organic synthesis. Despite the existence of various decarboxylative transformation reactions such as Kolbe dimerization, these methods still exhibit certain limitations that present opportunities for further improvement. In this account, we present our recent studies on the application of photocatalytic decarboxylative transformation that allows the divergent transformation of carboxylic acids.