高分子纳米吸附剂去除纺织废水中的重金属

IF 0.1 Q4 ENGINEERING, CHEMICAL Journal of the Pakistan Institute of Chemical Engineers Pub Date : 2023-03-14 DOI:10.54693/piche.05111
Waqar Ali Khan, Hafiz Miqdad Masood, Khurram Shahzad, Muhammad Imran, Najaf Ali, Ahmad Naveed
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引用次数: 0

摘要

纺织工业废水中含有杂质和重金属离子,对人类社会造成危害,可通过食物链危害人体健康。在排水前吸附重金属离子,使废水对水生生物和人类健康安全。高分子纳米吸附剂对重金属的吸附是一种新兴的吸附技术,它比活性炭等传统吸附剂更有效。当吸附剂用量为1.0 g/L时,在pH为9.0的条件下,Co的吸附剂吸附剂表面的负电荷产生的静电引力增大,有利于吸附阳离子。在15分钟的保留时间开始时,由于有更多的吸附位点,金属离子的吸附速度更快,但由于水合离子的电荷密度和直径可能导致部分解吸,因此保留时间的进一步增加降低了吸附速度。同样,在7.0 pH下,当吸附剂用量为1.0 g/L时,Cu的最大吸附性为95%。
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Removal of heavy metals from wastewater of textile industry using polymeric nano-adsorbent
Wastewater of textile industry having impurities and heavy metal ions cause problems in human society that can endanger the human health through food chain. Adsorption of heavy metal ions before draining makes wastewater safe for aquatic life and human health. Now a days adsorption of heavy metal through polymeric Nano adsorbent is the emerging technology which is more efficient than conventional adsorbents like activated carbon. The pH 9.0 gave maximum 96% sorption of Co at 1.0 g/L adsorbent dosage, due to increased electrostatic force of attraction produced by the negative charge at the surface of sorbent which is favorable for adsorbing cationic species. In the beginning of 15 minutes retention time, metal ions adsorption was faster due to availability of more number of adsorptive sites but further increase of retention time decreased the sorption due to partial desorption that may occur due to the charge density and diameter of hydrated ions. Similarly in case of Cu, the maximum sorption was 95% at 7.0 pH using 1.0 g/L adsorbent dosage.
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