TiO2添加剂组成对BaFe12O19磁性陶瓷物理磁性能、晶体结构和微观结构的影响

Endah Puspita, Nur Rahmah, Marzuki Naibaho, Ramlan Ramlan
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摘要

本研究采用粉末冶金法制备六铁体钡(BaFe<sub>12</sub>O<sub>19</sub>)磁性陶瓷,并添加0%:0.3%:0.6%和0.9%变化的二氧化钛(TiO<sub>2</sub>)添加剂。本研究使用的表征是密度、孔隙度、x射线衍射(XRD)、扫描电子显微镜(SEM)、振动样品磁强计(VSM)和k系列脉冲磁化仪的测量。根据密度和孔隙度测量结果,最高值分别为4.95 g/cm3和5.45%。XRD结果表明:BaFe<sub>12</sub>O<sub>19</sub>阶段有一些杂质在0% (Fe< sub> 2 & lt; / sub> O< sub> 3 & lt; / sub>), 0.3%和0.9% (Ti< sub> 6 & lt; / sub> O< sub> 11 & lt; / sub>),和0.6% (Ti< sub> 4 & lt; / sub> O< sub> 7 & lt; / sub>)。SEM结果表明:TiO<sub>2</sub>-BaFe<sub>12</sub>O<sub>19</sub>晶粒尺寸为0.5 ~ 1.5 μm,空腔尺寸为0.25 ~ 0.9 μm。VSM结果显示,Mr为1489 kG, Ms为3235 kG, Hc为1758 kOe, Bhmax为0867 MGOe。k系列脉冲式磁化器的结果表明,在0.6%和0%的变化下,最大和最低磁通量分别为272.65高斯和218.10高斯。
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Effect of The Composition of TiO2 Additives on The Physical and Magnetic Properties Crystal Structure and Microstructure of BaFe12O19 Magnetic Ceramics

In this research, the manufacture of barium hexaferrite (BaFe12O19) magnetic ceramics and the addition of titanium dioxide (TiO2) additives with variations of 0%: 0.3%: 0.6% and 0.9% used the powder metallurgical method. The characterization used in this study is the measurement of density, porosity, X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), Vibrating Sample Magnetometer (VSM), and Impulse Magnetizer K-Series. Based on the results of density and porosity measurements, the highest values were 4.95 g/cm3 and 5.45%, respectively. XRD results showed the formation of a BaFe12O19 phase with some impurities at 0% (Fe2O3), 0.3% and 0.9% (Ti6O11), and 0.6% (Ti4O7). The SEM results showed that the morphology of TiO2-BaFe12O19 was quite homogeneous, and the size and cavity ranged from 0.5 – 1.5 μm and 0.25 – 0.9 μm, respectively. VSM results show Mr, Ms, Hc, and Bhmax values of 1,489 kG, 3,235 kG, 1,758 kOe, and Bhmax of 0,867 MGOe, respectively. The results of the Impulse Magnetizer K-Series show the maximum and lowest magnetic flux values of 272.65 gauss and 218.10 gauss at 0.6% and 0% variation, respectively.

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