溶剂组成及铜离子掺杂染料花青素对提高染料敏化太阳能电池效率的影响

Novi Dyah Puspitasari, Fahru Nurosyid, Untung Riyadi, Sophia Dewi Nur Anisa, Kusumandari Kusumandari
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摘要

<p class="摘要">染料敏化太阳能电池(DSSC)的发展迅速,因为制造成本比硅太阳能电池更实惠。在本研究中,<em>花青素pigments< / em>被用作天然染料来源。花青素是一类黄酮类化合物,在酸性条件下最容易提取;因此,溶剂和酸组成的变化显著影响花青素的产量。本研究以火龙果皮为原料,采用不同甲醇组成的浸渍法提取花青素色素,并加入盐酸或柠檬酸(3/0;3/0.5;3/1)。本研究旨在通过改变溶剂组成和添加Cu离子掺杂来提高DSSC的效率。表征包括分别使用紫外-可见分光光度计,傅里叶变换红外(FTIR)和电流-电压测量吸光度,官能团和效率。结果表明:以甲醇/酸(3/0)为配比,加入Cu离子时,花青素染料的吸光度值和效率最高,为0.4102 Ω<sup>-1</sup>和0.016% .</p>
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The Impact of Solvent Composition and Copper (Cu) Ion Doping on Dye Anthocyanin on Increasing Dye-Sensitized Solar Cell (DSSC) Efficiency

The development of Dye Sensitized Solar Cells (DSSC) is increasing fast because fabrication costs are more affordable than silicon solar cells. In this study, anthocyanin pigments were used as a natural dye source. Anthocyanins are a group of flavonoids that can be extracted most proficiently in acidic conditions; therefore, variations in the composition of solvents and acids significantly impact anthocyanin yield. The anthocyanin pigments in this study were extracted from dragon fruit peels using a maceration method with variations in methanol composition and the addition of hydrochloric acid or citric acid (3/0; 3/0.5; 3/1). This study aims to improve the efficiency of DSSC by varying the solvent composition and adding Cu ion doping. The characterizations include measurement of absorbance, functional group, and efficiency using UV-Vis Spectrophotometer, Fourier Transform Infrared (FTIR), and current-voltage, respectively. The results show that anthocyanin dye with a composition of methanol/acid (3/0) and the addition of Cu ion produced the highest absorbance value and efficiency of 0.4102 Ω-1m-1 and 0.016%, respectively.

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