化学沉积法制备CuFe(1-x) CrxO4纳米结构的光学性质

Abdul Sami Fawzi Abdul Aziz, Hamoud Hamad Ahmed
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引用次数: 0

摘要

在(700℃)温度下,采用化学沉积法在尺寸为1cm (1cm)的玻璃基底上制备了质量比为(x = 0,0.2, 0.4, 0.6, 0.8, 1)的CuFe(1-x) CrxO4薄膜。对所制备薄膜的光学性质进行研究,包括记录波长范围(300-900 nm)的吸光度谱和光能间隙。此外,研究光学常数由消光系数、折射率以及介电常数的实部和虚部作为波长的函数来表示。当加入铬离子作为铁离子的替代品时,光学性质显示出一个峰的出现,在370 nm波长处的吸光度。该峰的强度随样品中铬含量的增加而直接增加。我们还观察到,能隙明显减小到3eV。当百分比增加到x=0.8时,由于尺寸减小,光能隙值略有增加到3.1eV。
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Optical Properties of (CuFe(1-x) CrxO4) Nanostructures Prepared by Chemical Deposition Method
Thin films of (CuFe(1-x) CrxO4) with weight ratios (x = 0, 0.2, 0.4, 0.6, 0.8, 1) were prepared using the chemical deposition method on glass bases with dimensions x 1cm (1cm) at (700°C) temperature. Studying the optical properties of the prepared films includes recording the absorbance spectrum and the optical energy gap for the wavelength range (300-900 nm). Moreover, studying the optical constants is represented by the extinction coefficient, the refractive index, and the real and imaginary part of the dielectric constant as a function of wavelength. The optical properties show the appearance of a peak, an absorbance at a wavelength of 370 nm when adding a chromium ion as a substitute for the iron ion. The intensity of this peak increases directly with the increase in the percentage of chromium in the sample. It was also observed that the energy gap decreases significantly to 3eV. There is a slight increase in the value of the optical energy gap to 3.1eV when the percentage increases to x=0.8 due to decrease in size.
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