熔点法制备Ge60Se40-xTex合金的局域和扩展能态密度计算

IF 1.2 4区 材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Chalcogenide Letters Pub Date : 2023-09-20 DOI:10.15251/cl.2023.209.649
J. H. Azzawi, B. A. Ahmed, K. A. Jasim, E. M. T. Salman
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引用次数: 0

摘要

研究了x = 0、5、10、15、20时Ge60Se40-xTex合金的直流导电性。样品呈圆盘状,厚度为0.25 ~ 0.30 cm,直径为1.5 cm。样品在每平方厘米6吨的压力下被压制,使用一吨液压机。它们是用一吨水压机用水压机压成的。熔点技术用于制备样品。从室温到475 K记录了连续的电导率特性。实验数据表明,与其他样品相比,含15% Te的玻璃具有最高的导电性,允许最大的电流通过样品。因此,发现直流电导率随Te浓度的增加而增加。由于温度对样品晶体结构的影响,样品的电导率表现出非欧姆行为,这表明样品在部分替换后仍保持半导电状态。在高温、中温和低温下,还观察到每种样品的三种传导机制。计算了费米能级的局部态密度和扩展态密度以及电导参数,发现它们都随Te浓度的变化而变化。
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Calculation of the localized and extended energy states density for Ge60Se40-xTex alloy prepared by melting point method
The DC electrical conductivity properties of Ge60Se40-xTex alloy with x = 0, 5, 10, 15 and 20). The samples were formed in the form of discs with the thickness of 0.25–0.30 cm and the diameter of 1.5 cm. Samples were pressed under a pressure of 6 tons per cm2 , using a ton hydraulic press. They were prepared after being pressed using a ton hydraulic press using a hydraulic press. Melting point technology use to preper the samples. Continuous electrical conductivity properties were recorded from room temperature to 475 K. Experimental data indicates that glass containing 15% Te has the highest electrical conductivity allowing maximum current through the sample compared to Lu with other samples. Therefore, it is found that the DC conductivity increases with increasing Te concentration. The electrical conductivity properties show non-ohmic behavior due to the effects of temperature on the crystal structure of the samples, which indicates that the samples remain semi-conductive after partial replacement. Three conduction mechanisms are also observed for each sample at high, medium, and low temperatures. The Fermi level local and extended state densities and conductance parameters were calculated, and all were found to change with the change of Te concentration.
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来源期刊
Chalcogenide Letters
Chalcogenide Letters MATERIALS SCIENCE, MULTIDISCIPLINARY-PHYSICS, APPLIED
CiteScore
1.80
自引率
20.00%
发文量
86
审稿时长
1 months
期刊介绍: Chalcogenide Letters (CHL) has the aim to publish rapidly papers in chalcogenide field of research and appears with twelve issues per year. The journal is open to letters, short communications and breakings news inserted as Short Notes, in the field of chalcogenide materials either amorphous or crystalline. Short papers in structure, properties and applications, as well as those covering special properties in nano-structured chalcogenides are admitted.
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