介孔有序二氧化钛薄膜:一种先进的光催化平台

Plinio Innocenzi, Luca Malfatti
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引用次数: 0

摘要

介孔材料具有独特的结构特征,如高表面积、大孔体积和相互连接的孔网络,使其成为光催化的理想候选者。本文综述了介孔二氧化钛光催化膜的合成方法、表征技术及其光催化性能。本文首先简要介绍了二氧化钛光催化的化学物理过程。它强调了对具有增强表面积和光收集能力的高效光催化材料的需求。随后,讨论了制备介孔二氧化钛薄膜的合成方法,包括溶胶-凝胶化学、模板方法和自组装技术。重点是控制孔径、分布和膜厚以优化光催化性能。详细考察了合成参数对薄膜孔隙度、结晶度和比表面积的影响。此外,综述了该领域的最新进展,包括通过掺杂、表面改性和异质结构形成来提高介孔二氧化钛薄膜光催化性能的策略。这些方法旨在提高光吸收、电荷分离和反应物可及性,从而最大限度地利用太阳能进行高效光催化。综上所述,介孔二氧化钛薄膜作为有效的光催化材料具有很大的潜力。它们独特的结构特征,结合适当的合成和表征,有助于增强光催化性能。在这一领域的进一步研究和发展可能会导致设计和制造先进的介孔二氧化钛薄膜,用于广泛的环境和能源应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Mesoporous ordered titania films: An advanced platform for photocatalysis

Mesoporous materials possess unique structural characteristics, such as high surface area, large pore volume, and interconnected pore networks, which make them ideal candidates for photocatalysis. The objective of this review is to critically analyse the synthesis methods, characterization techniques, and photocatalytic performance of mesoporous titania films for photocatalysis. The article begins by providing a short overview of the chemical-physical processes involved in photocatalysis of titania. It highlights the need for efficient photocatalytic materials with enhanced surface area and light harvesting capabilities. Subsequently, the synthesis methods for creating mesoporous titania films are discussed, including sol-gel chemistry, templating approaches, and self-assembly techniques. Emphasis is placed on the control of pore size, distribution, and film thickness to optimize the photocatalytic performance. The influence of synthesis parameters on the film porosity, crystallinity, and surface area is examined in detail. Furthermore, the review highlights recent advancements in the field, including strategies to enhance the photocatalytic performance of mesoporous titania films through doping, surface modification, and heterostructure formation. These approaches aim to improve the light absorption, charge separation, and reactant accessibility, thus maximizing the utilization of solar energy for efficient photocatalysis. In conclusion, mesoporous titania films demonstrate great potential as effective photocatalytic materials. Their unique structural features, combined with proper synthesis and characterization, contribute to enhanced photocatalytic performance. Further research and development in this area may lead to the design and fabrication of advanced mesoporous titania films for a wide range of environmental and energy applications.

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来源期刊
CiteScore
21.90
自引率
0.70%
发文量
36
审稿时长
47 days
期刊介绍: The Journal of Photochemistry and Photobiology C: Photochemistry Reviews, published by Elsevier, is the official journal of the Japanese Photochemistry Association. It serves as a platform for scientists across various fields of photochemistry to communicate and collaborate, aiming to foster new interdisciplinary research areas. The journal covers a wide scope, including fundamental molecular photochemistry, organic and inorganic photochemistry, photoelectrochemistry, photocatalysis, solar energy conversion, photobiology, and more. It provides a forum for discussing advancements and promoting collaboration in the field of photochemistry.
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