介孔有序二氧化钛薄膜:一种先进的光催化平台

Plinio Innocenzi, Luca Malfatti
{"title":"介孔有序二氧化钛薄膜:一种先进的光催化平台","authors":"Plinio Innocenzi,&nbsp;Luca Malfatti","doi":"10.1016/j.jphotochemrev.2023.100646","DOIUrl":null,"url":null,"abstract":"<div><p>Mesoporous materials possess unique structural characteristics, such as high surface area, large pore volume, and interconnected pore networks, which make them ideal candidates for photocatalysis. The objective of this review is to critically analyse the synthesis methods, characterization techniques, and photocatalytic performance of mesoporous titania films for photocatalysis. The article begins by providing a short overview of the chemical-physical processes involved in photocatalysis of titania. It highlights the need for efficient photocatalytic materials with enhanced surface area and light harvesting capabilities. Subsequently, the synthesis methods for creating mesoporous titania films are discussed, including sol-gel chemistry, templating approaches, and self-assembly techniques. Emphasis is placed on the control of pore size, distribution, and film thickness to optimize the photocatalytic performance. The influence of synthesis parameters on the film porosity, crystallinity, and surface area is examined in detail. Furthermore, the review highlights recent advancements in the field, including strategies to enhance the photocatalytic performance of mesoporous titania films through doping, surface modification, and heterostructure formation. These approaches aim to improve the light absorption, charge separation, and reactant accessibility, thus maximizing the utilization of solar energy for efficient photocatalysis. In conclusion, mesoporous titania films demonstrate great potential as effective photocatalytic materials. Their unique structural features, combined with proper synthesis and characterization, contribute to enhanced photocatalytic performance. Further research and development in this area may lead to the design and fabrication of advanced mesoporous titania films for a wide range of environmental and energy applications.</p></div>","PeriodicalId":376,"journal":{"name":"Journal of Photochemistry and Photobiology C: Photochemistry Reviews","volume":null,"pages":null},"PeriodicalIF":12.8000,"publicationDate":"2023-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1389556723000771/pdfft?md5=4b8f64967ed43c2afa273cfa517e88bb&pid=1-s2.0-S1389556723000771-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Mesoporous ordered titania films: An advanced platform for photocatalysis\",\"authors\":\"Plinio Innocenzi,&nbsp;Luca Malfatti\",\"doi\":\"10.1016/j.jphotochemrev.2023.100646\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Mesoporous materials possess unique structural characteristics, such as high surface area, large pore volume, and interconnected pore networks, which make them ideal candidates for photocatalysis. The objective of this review is to critically analyse the synthesis methods, characterization techniques, and photocatalytic performance of mesoporous titania films for photocatalysis. The article begins by providing a short overview of the chemical-physical processes involved in photocatalysis of titania. It highlights the need for efficient photocatalytic materials with enhanced surface area and light harvesting capabilities. Subsequently, the synthesis methods for creating mesoporous titania films are discussed, including sol-gel chemistry, templating approaches, and self-assembly techniques. Emphasis is placed on the control of pore size, distribution, and film thickness to optimize the photocatalytic performance. The influence of synthesis parameters on the film porosity, crystallinity, and surface area is examined in detail. Furthermore, the review highlights recent advancements in the field, including strategies to enhance the photocatalytic performance of mesoporous titania films through doping, surface modification, and heterostructure formation. These approaches aim to improve the light absorption, charge separation, and reactant accessibility, thus maximizing the utilization of solar energy for efficient photocatalysis. In conclusion, mesoporous titania films demonstrate great potential as effective photocatalytic materials. Their unique structural features, combined with proper synthesis and characterization, contribute to enhanced photocatalytic performance. Further research and development in this area may lead to the design and fabrication of advanced mesoporous titania films for a wide range of environmental and energy applications.</p></div>\",\"PeriodicalId\":376,\"journal\":{\"name\":\"Journal of Photochemistry and Photobiology C: Photochemistry Reviews\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":12.8000,\"publicationDate\":\"2023-11-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S1389556723000771/pdfft?md5=4b8f64967ed43c2afa273cfa517e88bb&pid=1-s2.0-S1389556723000771-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Photochemistry and Photobiology C: Photochemistry Reviews\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1389556723000771\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Photochemistry and Photobiology C: Photochemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1389556723000771","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

摘要

介孔材料具有独特的结构特征,如高表面积、大孔体积和相互连接的孔网络,使其成为光催化的理想候选者。本文综述了介孔二氧化钛光催化膜的合成方法、表征技术及其光催化性能。本文首先简要介绍了二氧化钛光催化的化学物理过程。它强调了对具有增强表面积和光收集能力的高效光催化材料的需求。随后,讨论了制备介孔二氧化钛薄膜的合成方法,包括溶胶-凝胶化学、模板方法和自组装技术。重点是控制孔径、分布和膜厚以优化光催化性能。详细考察了合成参数对薄膜孔隙度、结晶度和比表面积的影响。此外,综述了该领域的最新进展,包括通过掺杂、表面改性和异质结构形成来提高介孔二氧化钛薄膜光催化性能的策略。这些方法旨在提高光吸收、电荷分离和反应物可及性,从而最大限度地利用太阳能进行高效光催化。综上所述,介孔二氧化钛薄膜作为有效的光催化材料具有很大的潜力。它们独特的结构特征,结合适当的合成和表征,有助于增强光催化性能。在这一领域的进一步研究和发展可能会导致设计和制造先进的介孔二氧化钛薄膜,用于广泛的环境和能源应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Mesoporous ordered titania films: An advanced platform for photocatalysis

Mesoporous materials possess unique structural characteristics, such as high surface area, large pore volume, and interconnected pore networks, which make them ideal candidates for photocatalysis. The objective of this review is to critically analyse the synthesis methods, characterization techniques, and photocatalytic performance of mesoporous titania films for photocatalysis. The article begins by providing a short overview of the chemical-physical processes involved in photocatalysis of titania. It highlights the need for efficient photocatalytic materials with enhanced surface area and light harvesting capabilities. Subsequently, the synthesis methods for creating mesoporous titania films are discussed, including sol-gel chemistry, templating approaches, and self-assembly techniques. Emphasis is placed on the control of pore size, distribution, and film thickness to optimize the photocatalytic performance. The influence of synthesis parameters on the film porosity, crystallinity, and surface area is examined in detail. Furthermore, the review highlights recent advancements in the field, including strategies to enhance the photocatalytic performance of mesoporous titania films through doping, surface modification, and heterostructure formation. These approaches aim to improve the light absorption, charge separation, and reactant accessibility, thus maximizing the utilization of solar energy for efficient photocatalysis. In conclusion, mesoporous titania films demonstrate great potential as effective photocatalytic materials. Their unique structural features, combined with proper synthesis and characterization, contribute to enhanced photocatalytic performance. Further research and development in this area may lead to the design and fabrication of advanced mesoporous titania films for a wide range of environmental and energy applications.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
CiteScore
21.90
自引率
0.70%
发文量
36
审稿时长
47 days
期刊介绍: The Journal of Photochemistry and Photobiology C: Photochemistry Reviews, published by Elsevier, is the official journal of the Japanese Photochemistry Association. It serves as a platform for scientists across various fields of photochemistry to communicate and collaborate, aiming to foster new interdisciplinary research areas. The journal covers a wide scope, including fundamental molecular photochemistry, organic and inorganic photochemistry, photoelectrochemistry, photocatalysis, solar energy conversion, photobiology, and more. It provides a forum for discussing advancements and promoting collaboration in the field of photochemistry.
期刊最新文献
Fluorescent fluorinated materials: A novel material for application in photodynamic therapy and designing chemical sensors Editorial Board Towards red-NIR emission of platinum(II) complexes Progress and promise of photoresponsive nanocarriers for precision drug delivery in cancer Editorial Board
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1