A. S. Lyadov, A. A. Kochubeev, Yu. V. Kostina, Le Anh Tuan, Pham Dai Duong
{"title":"越南热带气候对尿素增稠剂合成润滑脂性能的影响","authors":"A. S. Lyadov, A. A. Kochubeev, Yu. V. Kostina, Le Anh Tuan, Pham Dai Duong","doi":"10.1134/S0965544123060233","DOIUrl":null,"url":null,"abstract":"<p>This study investigated, for the first time, the effects of the tropical climate of Vietnam on the properties of synthetic greases with urea thickeners. The greases were exposed to seven-month field tests at climatic test stations of the Joint Russian–Vietnamese Tropical Research and Technological Center in three regions of Vietnam. This short-term exposure decreased the ultimate strength and affected the colloidal stability of the samples (in the colloidal stability measurements, the amount of separated oil was reduced). At the same time, the chemical composition of the greases remained essentially unchanged, as confirmed by IR spectroscopy. It would be reasonable to assume that the degradation of polyurea greases in tropical climates is primarily associated with their colloidal structural changes. This assumption, however, requires confirmation in further research that should involve longer exposure and a larger number of grease samples prepared from different base oils. It was additionally found that introducing a heterogeneous modifier into polyurea greases impairs their stability in tropical climate.</p>","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":null,"pages":null},"PeriodicalIF":1.3000,"publicationDate":"2023-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effects of the Tropical Climate of Vietnam on the Properties of Synthetic Greases with Urea Thickeners\",\"authors\":\"A. S. Lyadov, A. A. Kochubeev, Yu. V. Kostina, Le Anh Tuan, Pham Dai Duong\",\"doi\":\"10.1134/S0965544123060233\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This study investigated, for the first time, the effects of the tropical climate of Vietnam on the properties of synthetic greases with urea thickeners. The greases were exposed to seven-month field tests at climatic test stations of the Joint Russian–Vietnamese Tropical Research and Technological Center in three regions of Vietnam. This short-term exposure decreased the ultimate strength and affected the colloidal stability of the samples (in the colloidal stability measurements, the amount of separated oil was reduced). At the same time, the chemical composition of the greases remained essentially unchanged, as confirmed by IR spectroscopy. It would be reasonable to assume that the degradation of polyurea greases in tropical climates is primarily associated with their colloidal structural changes. This assumption, however, requires confirmation in further research that should involve longer exposure and a larger number of grease samples prepared from different base oils. It was additionally found that introducing a heterogeneous modifier into polyurea greases impairs their stability in tropical climate.</p>\",\"PeriodicalId\":725,\"journal\":{\"name\":\"Petroleum Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2023-12-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Petroleum Chemistry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0965544123060233\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Petroleum Chemistry","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1134/S0965544123060233","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Effects of the Tropical Climate of Vietnam on the Properties of Synthetic Greases with Urea Thickeners
This study investigated, for the first time, the effects of the tropical climate of Vietnam on the properties of synthetic greases with urea thickeners. The greases were exposed to seven-month field tests at climatic test stations of the Joint Russian–Vietnamese Tropical Research and Technological Center in three regions of Vietnam. This short-term exposure decreased the ultimate strength and affected the colloidal stability of the samples (in the colloidal stability measurements, the amount of separated oil was reduced). At the same time, the chemical composition of the greases remained essentially unchanged, as confirmed by IR spectroscopy. It would be reasonable to assume that the degradation of polyurea greases in tropical climates is primarily associated with their colloidal structural changes. This assumption, however, requires confirmation in further research that should involve longer exposure and a larger number of grease samples prepared from different base oils. It was additionally found that introducing a heterogeneous modifier into polyurea greases impairs their stability in tropical climate.
期刊介绍:
Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas.
Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.