利用圆锥电子束和有芯线通过三维打印制造 Ti-6Al-4V+40%TiC 金属基复合材料的新方法。第 1 部分:工艺的主要特点、微观结构的形成以及 3D 打印材料的基本特性

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摘要

本文研究了一种基于碳化钛颗粒增强的 Ti-6Al-4V 钛合金的金属基复合材料以及由这种复合材料和 Ti-6Al-4V 合金层组成的分层结构的增材制造新方法。该方法基于锥形电子束的三维打印,使用的是一种特殊的有芯线,其成分与金属基复合材料一致。文中介绍了生产这种线材的问题、使用这种线材时三维打印工艺的特点,以及打印复合材料的微观结构和相组成的形成特点。在三维打印过程中,碳化钛颗粒与 Ti-6Al-4V 熔体的润湿问题,以及固体 TiC 颗粒在熔体中可能产生的热重效应(漂浮或淹没),都通过附加实验进行了详细研究。实验还显示了线材成分的各个组成部分对微观结构的形成及其在打印层横截面上的均匀性的影响。结果表明,可以控制均匀结构状态的形成,并在 Ti-6Al-4V 底板上印制金属基复合层,以获得足够高的硬度值(600 HV 以上)。
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New Approach for Manufacturing Ti–6Al–4V+40%TiC Metal-Matrix Composites by 3D Printing Using Conic Electron Beam and Cored Wire. Pt. 1: Main Features of the Process, Microstructure Formation and Basic Characteristics of 3D Printed Material
In this paper, a new approach for additive manufacturing metal-matrix composites based on Ti–6Al–4V titanium alloy reinforced with titanium carbide particles, as well as layered structures consisted of such composite and Ti–6Al–4V alloy layers is considered. The approach is based on 3D printing with a conical electron beam using a special cored wire, whose composition corresponds to metal-matrix composite. The issues of production such a wire, the features of the 3D printing process, when using it, as well as the features of formation of the microstructure and phase composition of the printed composite material are described. The issues of titanium-carbide particles’ wetting with Ti–6Al–4V melt during process of 3D printing, as well as possible thermogravitational effects (floating or drowning) for solid TiC particles within the melt are considered in detail with additional experiments. The influence of individual components of the wire composition on the formation of the microstructure and its uniformity over the cross section of the printed layer is shown. The possibility of controlling the formation of homogeneous structural state and obtaining sufficiently high values of the hardness (of above 600 HV) of the metal-matrix composite layer printed on the Ti–6Al–4V baseplate is shown.
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Progress in Additive Manufacturing New Approach for Manufacturing Ti–6Al–4V+40%TiC Metal-Matrix Composites by 3D Printing Using Conic Electron Beam and Cored Wire. Pt. 2: Layered MMC/Alloy Materials, Their Main Characteristics, and Possible Application as Ballistic Resistant Materials Multiband Quantum Materials Synthetic-Hydroxyapatite-Based Coatings on the Ultrafine-Grained Titanium and Zirconium Surface Development of High-Entropy Shape-Memory Alloys: Structure and Properties
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