开发用于水处理的环保型改性生物吸附剂

Minira Aghahuseynova, Leyla Vazirova
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引用次数: 0

摘要

科学研究的结果表明,基于 Fe3O4 纳米粒子和 AlgBT 复合材料合成的纯吸附剂,由于含有双氢氧化物和海藻酸基质,吸附能力有所提高。复合物的形成过程遵循最大限度地继承原始配位化合物结构特征的原则,这使得预测和实现新化合物的假定结构成为可能。所有这些都大大提高了所开发吸附剂对磷酸盐离子的吸附能力。因此,以粘土为基础的改性吸附剂是一个特别令人感兴趣的领域。目前的研究构建并描述了改性吸附剂,然后在实验室中进行了测试,以确定它们对磷酸盐的吸附效果。本研究使用光谱技术(扫描电镜、傅立叶变换红外光谱、X 射线衍射和 X 射线衍射分析方法)来检测基于海藻酸盐、膨润土和纳米颗粒的改良型生态友好吸附剂的结构和理化特性。藻酸盐核心可进行物理和化学修饰,并可利用其中存在的活性 COOH 和 OH 基团参与各种磷酸盐阴离子吸附方法。我们确定了改性 Fe3O4NPs@AlgBT 的吸附效率。在开始吸附后的 10 小时内,吸附-Na2HPO4 水溶液系统达到平衡,而三分之二的吸附阴离子在最初的两小时内进入固相。改性的 Fe3O4NPs@AlgBT 对磷酸盐离子的极限吸附量达到 410 mg/g,因此可以作为一种有效的吸附剂用于工业废水处理。
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Development of environmentally-friendly modified bioadsorbents for water treatment
As a result of scientific research, it was found that synthesized pure sorbents based on a composite of Fe3O4 nanoparticles and AlgBT have an increased adsorption capacity due to the inclusion of double hydroxides and an alginate matrix. The processes of complex formation occur according to the principle of maximum inheritance of the structural features of the original coordination compounds, which make it possible to predict and implement the hypothetical structures of new compounds. All this significantly improves the adsorption capacity of the developed adsorbents with respect to phosphate ions. Modified sorbents with a clay basis are therefore a particularly intriguing field. The current research constructed and described modified sorbents, and then conducted tests in the laboratory to determine how well they absorbed phosphate. This study used spectroscopic techniques (SEM, FTIR, X-ray diffraction, and XRD analytical methods) to examine the structure and physicochemical characteristics of improved ecologically friendly sorbents based on alginates, bentonite, and nanoparticles. The alginate core may be physically and chemically modified and can take part in a variety of phosphate anion adsorption methods thanks to the active COOH and OH groups that are present there. The sorption efficiency was established for a modified Fe3O4NPs@AlgBT. Equilibrium in the system sorbent-an aqueous solution of Na2HPO4 is established in 10 hours after the start of sorption, while two-thirds of all sobbed anions pass into the solid phase during the first two hours. The limiting sorption of phosphate ions on modified Fe3O4NPs@AlgBT reaches 410 mg/g, which makes it possible to offer it as an effective sorbent for industrial wastewater treatment
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来源期刊
EUREKA: Physics and Engineering
EUREKA: Physics and Engineering Engineering-Engineering (all)
CiteScore
1.90
自引率
0.00%
发文量
78
审稿时长
12 weeks
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