可生物降解的掺铜改性 45S5 玻璃的致密化-结晶行为

Ahad Saeidi, S. Banijamali, M. Heydari
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摘要

在当前的研究工作中,采用熔融程序制备了含有不同数量氧化铜(1、3 和 5 重量比)的改性 45S5 玻璃,并在不同温度下烧结后对其物理性质进行了表征。掺铜玻璃的表征采用了多种分析技术,包括 X 射线衍射仪、差热分析和扫描电子显微镜。为此,对掺铜玻璃的致密化-结晶和烧结温度的优化进行了系统研究。差热分析显示,所研究玻璃的结晶温度(Tc)在 800 ℃ 以上有微弱的放热峰。这一分析表明,氧化铜对改性 45S5 玻璃的热性能影响有限。在 600 至 850 °C 的温度范围内对玻璃试样的致密化行为进行了研究。发现最佳致密化温度分别为 650 ℃。结果表明,铜离子存在于所研究的玻璃结构中,导致烧结后形成多孔结构。看来铜离子在烧结过程中产生了氧气,促进了蜂窝状泡沫结构的形成。
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Densification-crystallization behavior of biodegradable copper-doped modified 45S5 glasses
In the current work, modified 45S5 glasses containing different amounts of copper oxide (1, 3, and 5 weight ratios) were prepared using melting procedure and characterized for their physical properties after sintering at various temperatures. Characterization of the copper doped glasses was performed using various analytical techniques, including X-ray diffractometry, differential thermal analysis, and scanning electron microscopy. To this purpose, a systematic study was conducted on densification-crystallization of the copper doped glasses and optimizing sintering temperature. Differential thermal analysis revealed weak exothermic peaks located above 800 °C, corresponding to the crystallization temperature (Tc) of the studied glasses. This analysis suggests that copper oxide has a limited effect on the thermal properties of the modified 45S5 glasses. Densification behavior of glass specimens was studied at temperatures ranging from 600 to 850 °C. The optimal densification temperature was found to be 650 °C, respectively. The results indicated that the presence of copper ions in the structure of studied glasses results in the formation of porous structures after sintering. It seems that copper ions generate oxygen gas during sintering and promote the formation of a cellular foam structures.
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