Sedimentary records of polycyclic aromatic hydrocarbons and organochlorine pesticides to reconstruct anthropogenic activities in Lake Issyk-Kul region (Kyrgyzstan), and their effects on the lake environment

Vertical distributions of polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCPs) in a sediment core from Lake Issyk-Kul are powerful tools for reconstructing historical anthropogenic activities over the past 350 years. Four periods were identified according to the variations in these environmental proxies. Period Ⅰ (1670s–1800s) corresponds to a phase of limited anthropogenic activity reflected by the lowest ΣPAH₁₆ concentrations, mainly from biomass combustion and petrogenic processes. Along with pronounced deforestation due to wildfires documented in the pollen record, a similar decrease in PAHs suggests that PAHs were most likely generated by natural sources around Lake Issyk-Kul during this period. Period Ⅱ (1800s–1930s) reflects increasing agricultural activities with fluctuations in various PAH concentrations. Anthropogenic biomass-derived PAH inputs from agricultural activities gradually replaced natural inputs to Lake Issyk-Kul, coinciding with several historical events. However, natural factors still mainly controlled changing lake levels before the 1930s. Period Ⅲ (1930s–1970s) corresponds to rapid development of agricultural activities, inferred by slight increases in ΣPAH₁₆ concentrations dominated by coal-derived PAHs and a considerable increase in ΣOCP₁₈ concentrations. Concentrated agricultural activities around Lake Issyk-Kul significantly influenced environmental changes in grain size and water level in the lake. Period Ⅳ (post-1970 s) corresponds to intensive industrial and urban activities, including a 10-year economic depression (1990s–2000s), characterized by the highest ΣPAH₁₆ concentrations mainly from petroleum combustion followed by a sharp drop after the 1990s as the dissolution of the Soviet Union. Industrialization and urbanization in study area have changed the trophic state of Lake Issyk-Kul, particularly in recent years. Climate change has also induced “lateral remobilization” of contaminants, increasing pollution levels in this mountain lake.