从水的三相点到铟的凝固点的 ITS-90 子范围内的新插值公式

IF 2.1 3区 工程技术 Q2 INSTRUMENTS & INSTRUMENTATION Metrologia Pub Date : 2024-01-08 DOI:10.1088/1681-7575/ad1bfb
Kang Lan, Lide Fang, Ying Wang, Zhiru Kang, Suli Sang
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引用次数: 0

摘要

对于 0.01 ℃ 以上的所有子范围,除了水的三相点(TPW)到镓的熔点之间的插值以外,ITS-90 上的温度都是在没有镓的熔点的情况下指定的。本研究提出了一个从水的三重点到铟的凝固点的新插值方程,它是一个分数三阶多项式,有两个系数,由标准铂电阻温度计(SPRT)在镓的熔点(WGa)和铟的凝固点(WIn)的电阻比测量值决定。一组来自不同国家和实验室的 30 个 SPRT 样本用于量化这种新插值法与 ITS-90 之间的比较。分析表明,在相同的子范围内,与 ITS-90 相比,重现性明显提高。从 TPW 到镓熔点的重叠子范围不一致性 (SRI) 峰值从 0.91 mK 降至 0.21 mK。与 ITS-90 相比,新方程 SRI 峰值的平均值和标准偏差都降低了约 4 倍(平均值从 0.20 mK 降至 0.05 mK,标准偏差从 0.32 mK 降至 0.07 mK)。此外,还使用铜块在恒温水浴中比较了四个 SPRT 的数据集,对同一子范围的第 3 类非唯一性(NU3)进行了测定,结果表明,NU3 的范围从 ITS-90 的 -0.15 mK 至 0.25 mK 缩小到新插值方程的 -0.10 mK 至 0.15 mK。不确定度的传播调查表明,新方程在 30 ℃ 至 60 ℃ 的较短区间内仅使固定点的测量不确定度增加了 7%。
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A New Interpolation Equation in the ITS-90 Subrange from the Triple Point of Water to the Freezing Point of Indium
For all the subranges above 0.01 ℃, other than the interpolation between the triple point of water (TPW) to the melting point of gallium, temperatures on the ITS-90 are specified without the melting point of gallium. This study suggests a new interpolation equation in the subrange from the triple point of water to the freezing point of indium which is a polynomial of fractional third order with two coefficients to be determined by the measuring values of standard platinum resistance thermometers (SPRTs)’ resistance ratios at the melting point of gallium (WGa) and at the freezing point of indium (WIn). A sample set of 30 SPRTs from various countries and laboratories is used to quantify the comparisons between this new interpolation and the ITS-90. Analyses show that the reproducibility is significantly improved compared with the ITS-90 in the same subrange. The peak value of overlapping subrange inconsistencies (SRI) from TPW to the melting point of gallium is reduced from 0.91 mK to 0.21 mK. Both the mean and standard deviation of the SRI peak values for the new equation decrease by approximately a factor of four compared to those of the ITS-90 (mean decreasing form 0.20 mK to 0.05 mK and standard deviation decreasing form 0.32 mK to 0.07 mK). Type 3 non-uniqueness (NU3) determinations of the same subrange have also been looked into with a data set of four SPRTs compared in thermostatic baths using a copper block and the results show that NU3 scales down from a range -0.15 mK to 0.25 mK of the ITS-90 to -0.10 mK to 0.15 mK of the new interpolation equation. Propagation of Uncertainties investigation shows that the new equation inflates merely 7% the measurement uncertainties of fixed points in a relatively short interval from 30 ℃ to 60 ℃.
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来源期刊
Metrologia
Metrologia 工程技术-物理:应用
CiteScore
2.80
自引率
25.00%
发文量
137
审稿时长
12 months
期刊介绍: Published 6 times per year, Metrologia covers the fundamentals of measurements, particularly those dealing with the seven base units of the International System of Units (metre, kilogram, second, ampere, kelvin, candela, mole) or proposals to replace them. The journal also publishes papers that contribute to the solution of difficult measurement problems and improve the accuracy of derived units and constants that are of fundamental importance to physics. In addition to regular papers, the journal publishes review articles, issues devoted to single topics of timely interest and occasional conference proceedings. Letters to the Editor and Short Communications (generally three pages or less) are also considered.
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