固态电池技术的进步与挑战:固体电解质和负极创新的深入评述

Abniel Machín, Carmen Morant, F. Márquez
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引用次数: 0

摘要

本综述的主要目的是全面概述固态电池(SSB)的最新进展,重点关注固态电解质和阳极的最新进展。论文首先介绍了从液态电解质锂离子电池到先进固态电池的演变背景,重点强调了固态电池安全性和能量密度的提高。论文探讨了电动汽车和便携式电子产品等应用领域对高效、安全储能日益增长的需求。论文的主要部分分析了 SSB 技术的关键--固体电解质。论文将固体电解质分为聚合物型、氧化物型和硫化物型,讨论了它们的不同特性和应用适用性。综述还介绍了固态电池负极材料的进展,探讨了金属锂、硅和金属间化合物等材料,重点关注它们的容量、耐用性以及与固体电解质的兼容性。报告还探讨了集成这些负极材料所面临的挑战,如界面稳定性和锂枝晶的生长。本综述讨论了最新的分析技术、实验研究和计算模型,以了解和改进阳极-固体电解质界面。这些对于解决界面电阻和确保固态电池的长期稳定性和效率至关重要。最后,论文提出了未来的研究和发展方向,强调了固态电池在革新储能技术方面的潜力。本综述是学术界、研究人员和先进电池技术开发行业专业人士的重要资源。它详细概述了塑造固态电池未来的材料和技术,为这一快速发展的领域当前面临的挑战和潜在的解决方案提供了见解。
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Advancements and Challenges in Solid-State Battery Technology: An In-Depth Review of Solid Electrolytes and Anode Innovations
The primary goal of this review is to provide a comprehensive overview of the state-of-the-art in solid-state batteries (SSBs), with a focus on recent advancements in solid electrolytes and anodes. The paper begins with a background on the evolution from liquid electrolyte lithium-ion batteries to advanced SSBs, highlighting their enhanced safety and energy density. It addresses the increasing demand for efficient, safe energy storage in applications like electric vehicles and portable electronics. A major part of the paper analyzes solid electrolytes, key to SSB technology. It classifies solid electrolytes as polymer-based, oxide-based, and sulfide-based, discussing their distinct properties and application suitability. The review also covers advancements in anode materials for SSBs, exploring materials like lithium metal, silicon, and intermetallic compounds, focusing on their capacity, durability, and compatibility with solid electrolytes. It addresses challenges in integrating these anode materials, like the interface stability and lithium dendrite growth. This review includes a discussion on the latest analytical techniques, experimental studies, and computational models to understand and improve the anode–solid electrolyte interface. These are crucial for tackling interfacial resistance and ensuring SSBs’ long-term stability and efficiency. Concluding, the paper suggests future research and development directions, highlighting SSBs’ potential in revolutionizing energy storage technologies. This review serves as a vital resource for academics, researchers, and industry professionals in advanced battery technology development. It offers a detailed overview of materials and technologies shaping SSBs’ future, providing insights into current challenges and potential solutions in this rapidly evolving field.
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