从报废电子产品中进行可扩展的选择性黄金回收

Hengjun Shang, Yao Chen, Shuhui Guan, Yue Wang, Jiazhen Cao, Xinru Wang, Hexing Li, Zhenfeng Bian
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摘要

全球报废电子产品的快速积累对环境造成了灾难性的影响,因为这种宝贵的资源大部分都被填埋了。电子废弃物(e-waste)含有大量贵金属,以黄金(Au)为例,其含量远远超过天然矿物。从电子垃圾中回收这些金属是一条潜在的可持续发展之路,但目前的回收途径还不能满足这一要求。在这里,我们展示了一种光催化工艺,可以从不同形式的电子垃圾中选择性地、高效地、可扩展地提取金。溶解过程不超过 12 小时,进一步还原沥滤液可获得纯度高达 99.0% 的金属金。在大规模环境下,我们的系统可单批处理 10 公斤电子垃圾,回收 8.82 克金。通过将贵金属回收推进到更接近实际应用的水平,这项工作将为电子产品更可持续的未来做出贡献。使用温和试剂从电子垃圾中选择性回收金是一项挑战。据报道,现在有一种光催化技术可通过调节溶剂的 pH 值实现高选择性的金溶解。该工艺的规模已扩大到可以高效处理一批 10 千克的电子废物。
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Scalable and selective gold recovery from end-of-life electronics
The rapid accumulation of end-of-life electronics around the world has a disastrous impact on the environment because much of this otherwise valuable resource goes to landfills. Electronic waste (e-waste) contains significant amounts of precious metals, in the case of gold (Au), far in excess of those found in natural minerals. Recovering these metals from e-waste provides a potential sustainable path, but current recycling routes are not yet up to the task. Here we show a photocatalytic process that allows for selective, efficient and scalable extraction of Au from different forms of e-waste. The dissolution takes no more than 12 h, and further reducing the leachate yields Au metal with purity up to 99.0%. In a large-scale setting, our system can treat 10 kg of e-waste for a single batch and recover 8.82 g of Au. By advancing precious metal recycling to a level closer to practical implementation, this work will contribute to a more sustainable future for electronics. Selective recovery of gold from electronic waste using mild reagents is a challenge. Now a photocatalytic technology is reported to enable highly selective gold dissolution through solvent pH adjustment. This process is scaled up to allow for the efficient handling of a single batch of 10 kg of electronic waste.
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