V. V. Parshutin, A. V. Koval’, V. V. Gorinchoi, V. I. Lozan
{"title":"水杨酸异核络合物 {[FeSr2(SalH)2(Sal)2(NO3)(DMA)4]}n 对 St.","authors":"V. V. Parshutin, A. V. Koval’, V. V. Gorinchoi, V. I. Lozan","doi":"10.3103/S1068375524010137","DOIUrl":null,"url":null,"abstract":"<p>The corrosion process of steel St. 3 in water with the addition of a heteronuclear salicylate complex {[FeSr<sub>2</sub>(SalH)<sub>2</sub>(Sal)<sub>2</sub>(NO<sub>3</sub>)(DMA)<sub>4</sub>]}<sub><i>n</i></sub> by gravimetric, electrochemical, and physicochemical methods (X‑ray phase analysis, UV, IR and Mössbauer spectroscopy) has been studied. It has been shown that the introduction of the additive under study into a corrosive environment significantly reduces steel corrosion. Depending on the duration of the tests and the concentration of the inhibitor, the corrosion rate is reduced by 5.1–11.1 times with a degree of protection of 80.5–91.0%. A mechanism of inhibition has been proposed. The inclusion of products of interaction of ionized iron with the complex in the coating layers has been proven.</p>","PeriodicalId":782,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"60 1","pages":"109 - 121"},"PeriodicalIF":0.9000,"publicationDate":"2024-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of Heteronuclear Salicylate Complex {[FeSr2(SalH)2(Sal)2(NO3)(DMA)4]}n on Corrosion of Steel St. 3 in Water\",\"authors\":\"V. V. Parshutin, A. V. Koval’, V. V. Gorinchoi, V. I. Lozan\",\"doi\":\"10.3103/S1068375524010137\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The corrosion process of steel St. 3 in water with the addition of a heteronuclear salicylate complex {[FeSr<sub>2</sub>(SalH)<sub>2</sub>(Sal)<sub>2</sub>(NO<sub>3</sub>)(DMA)<sub>4</sub>]}<sub><i>n</i></sub> by gravimetric, electrochemical, and physicochemical methods (X‑ray phase analysis, UV, IR and Mössbauer spectroscopy) has been studied. It has been shown that the introduction of the additive under study into a corrosive environment significantly reduces steel corrosion. Depending on the duration of the tests and the concentration of the inhibitor, the corrosion rate is reduced by 5.1–11.1 times with a degree of protection of 80.5–91.0%. A mechanism of inhibition has been proposed. The inclusion of products of interaction of ionized iron with the complex in the coating layers has been proven.</p>\",\"PeriodicalId\":782,\"journal\":{\"name\":\"Surface Engineering and Applied Electrochemistry\",\"volume\":\"60 1\",\"pages\":\"109 - 121\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2024-03-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Surface Engineering and Applied Electrochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://link.springer.com/article/10.3103/S1068375524010137\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface Engineering and Applied Electrochemistry","FirstCategoryId":"1085","ListUrlMain":"https://link.springer.com/article/10.3103/S1068375524010137","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"Engineering","Score":null,"Total":0}
Effect of Heteronuclear Salicylate Complex {[FeSr2(SalH)2(Sal)2(NO3)(DMA)4]}n on Corrosion of Steel St. 3 in Water
The corrosion process of steel St. 3 in water with the addition of a heteronuclear salicylate complex {[FeSr2(SalH)2(Sal)2(NO3)(DMA)4]}n by gravimetric, electrochemical, and physicochemical methods (X‑ray phase analysis, UV, IR and Mössbauer spectroscopy) has been studied. It has been shown that the introduction of the additive under study into a corrosive environment significantly reduces steel corrosion. Depending on the duration of the tests and the concentration of the inhibitor, the corrosion rate is reduced by 5.1–11.1 times with a degree of protection of 80.5–91.0%. A mechanism of inhibition has been proposed. The inclusion of products of interaction of ionized iron with the complex in the coating layers has been proven.
期刊介绍:
Surface Engineering and Applied Electrochemistry is a journal that publishes original and review articles on theory and applications of electroerosion and electrochemical methods for the treatment of materials; physical and chemical methods for the preparation of macro-, micro-, and nanomaterials and their properties; electrical processes in engineering, chemistry, and methods for the processing of biological products and food; and application electromagnetic fields in biological systems.