用合成的 MgFe2O4 纳米粒子去除水溶液中的 Pb2+

Nguyen Nho Dung, Phan Thi Kim Thu, Nguyen Thanh Binh, Nguyen Giang Nam, Nguyen Mau Thanh
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摘要

本文采用水热法合成了纳米级镁铁氧体(MgFe2O4)材料。通过 X 射线衍射(XRD)和扫描电子显微镜(SEM)分析了镁铁氧体的尺寸和微观结构。利用氮吸附-解吸法测定了制备材料的表面积(Brunauer - Emmett - Teller (BET))和孔隙率。研究了新型磁性吸附剂对 Pb2+ 的吸附行为。通过研究锰铁氧体用量等操作变量的影响,确定了吸附剂的吸附特性和 Pb2+ 去除效率。当 pH 值等于 5、温度为 25 °C、接触时间为 24 小时时,使用 0.1 g/L MgFe2O4 所获得的最大 Pb2+ 吸附能力为 16.08(mg/g)。
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Synthesized MgFe2O4 nanoparticles to remove Pb2+ from aqueous solution
In the present paper, nanosized magnesium ferrite (MgFe2O4) material is synthesized by the hydrothermal method. The size and microstructure of magnesium ferrite were analyzed based on X-ray diffraction (XRD), scanning electron microscopy (SEM). The nitrogen adsorption-desorption was used for determination of surface area (Brunauer – Emmett – Teller (BET)) and porosity of the fabricated material. The adsorption behavior of Pb2+ using a new magnetic adsorbent is investigated. The adsorption characteristic and Pb2+ removal efficiency of the adsorbent have been determined by investigating the influence of operating variables such as dosage of manganese ferrite. The maximum Pb2+ sorption capacity was found to be 16,08 (mg/g) and obtained using 0,1 g/L MgFe2O4 when pH equals 5, a temperature of 25 °C, and contact time as 24 h. The Langmuir and Freundlich models were used to fit the experimental data and these showed good correlations.
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