关于金属有机框架材料 MIL-101(Cr) 去除偶氮染料能力的研究

Phung Khac Nam Ho, Nguyen Ngoc Linh, Mai Quoc Long, La Duc Duong, Nguyen Thi Hoai Phuong, Nguyen Thi Hong Phuong
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摘要

MIL-101(Cr)由 1,4-苯二羧酸盐和铬三聚体桥组成,具有泽型和中等孔隙结构,以及较大的 BET 比表面积,这是它成为环境修复应用领域主要材料的基础。本研究采用水热法合成了 MIL-101(Cr)金属有机框架。所形成的材料具有清晰的结晶形态,八面体尺寸为 100-300 nm。XRD 图显示 MIL-101(Cr)在 21.10o 和 26,73o 处出现峰值。通过 N2 吸附等温线法计算得出,这种材料的表面积约为 2,900 m2/g。该材料可通过同步光催化吸附机制去除有机染料。对初始浓度为 10 ppm 的甲基橙的去除率超过 90%。
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Study on the ability to remove azo dyes of the metal-organic framework material MIL-101(Cr)
MIL-101(Cr) is formed from 1,4- benzene dicarboxylate and chromium trimer bridges and possesses a zeotype and medium pore structure along with a large BET-specific surface area, the bases for it to be a leading material in environmental remediation applications. This study synthesized the MIL-101(Cr) metal-organic framework using the hydrothermal method. The formed materials have sharp crystalline morphology octahedral size from 100-300 nm. XRD plot showing peaks at 21.10o and 26,73o assigned to MIL-101(Cr). The surface area of this material calculated by the N2 adsorption isotherm method gives the result of ~ 2,900 m2/g. This material can remove organic dyes by the simultaneous photocatalytic adsorption mechanism. The ability to remove methyl orange at an initial concentration of 10 ppm was over 90%.
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