Youngeun Lee, Hyo Jeong Kim, Min Woo Kim, Jin Miyawaki, Han Gi Chae, Youngho Eom
{"title":"基于全生物质的琼脂和纤维素纳米晶体强纳米复合纤维及其染料去除应用","authors":"Youngeun Lee, Hyo Jeong Kim, Min Woo Kim, Jin Miyawaki, Han Gi Chae, Youngho Eom","doi":"10.1007/s13367-024-00089-y","DOIUrl":null,"url":null,"abstract":"<div><p>Fiber-based commodities represent a substantial fraction of plastic waste, leading to environmental harm. Discarded sanitary masks and fishing equipment undergo degradation, generating microfiber plastics, thereby presenting a notable hazard to both human health and the ecosystem. In this study, mechanically strong and environmentally friendly nanocomposite fibers were prepared by dry-jet wet spinning. The all-biomass-based fibers comprised agar and cellulose nanocrystals (CNC) as the matrix and nanofiller, respectively, and were highly miscible in deionized water as a cosolvent. Based on rheological characterization, the optimal spinning concentration and temperature were set to 13% (w/v) and 95 °C, respectively. The dry-jet wet-spun agar-based fibers exhibited remarkable mechanical performance compared with previously reported agar-based materials. In particular, the 1 wt% CNC (with respect to the agar amount) simultaneously improved the Young’s modulus, strength, and toughness by 8.3, 4.8, and 16.4% (2.6 GPa, 93.5 MPa, and 7.8 MJ m<sup>−3</sup>), respectively, compared to those of the control agar fibers (2.4 GPa, 89.2 MPa, and 6.7 MJ m<sup>−3</sup>), overcoming the trade-off of stiffness-toughness for conventional nanocomposite systems. In addition, the agar/CNC nanocomposite fibers rapidly adsorbed Methylene blue within 90 min, which is significantly faster than that of the film-type agar adsorbent. Therefore, all-biomass-based agar/CNC fibers are a promising remedy for alleviating water pollution.</p></div>","PeriodicalId":683,"journal":{"name":"Korea-Australia Rheology Journal","volume":null,"pages":null},"PeriodicalIF":2.2000,"publicationDate":"2024-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"All-biomass-based strong nanocomposite fibers of agar and cellulose nanocrystals and their dye removal applications\",\"authors\":\"Youngeun Lee, Hyo Jeong Kim, Min Woo Kim, Jin Miyawaki, Han Gi Chae, Youngho Eom\",\"doi\":\"10.1007/s13367-024-00089-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Fiber-based commodities represent a substantial fraction of plastic waste, leading to environmental harm. Discarded sanitary masks and fishing equipment undergo degradation, generating microfiber plastics, thereby presenting a notable hazard to both human health and the ecosystem. In this study, mechanically strong and environmentally friendly nanocomposite fibers were prepared by dry-jet wet spinning. The all-biomass-based fibers comprised agar and cellulose nanocrystals (CNC) as the matrix and nanofiller, respectively, and were highly miscible in deionized water as a cosolvent. Based on rheological characterization, the optimal spinning concentration and temperature were set to 13% (w/v) and 95 °C, respectively. The dry-jet wet-spun agar-based fibers exhibited remarkable mechanical performance compared with previously reported agar-based materials. In particular, the 1 wt% CNC (with respect to the agar amount) simultaneously improved the Young’s modulus, strength, and toughness by 8.3, 4.8, and 16.4% (2.6 GPa, 93.5 MPa, and 7.8 MJ m<sup>−3</sup>), respectively, compared to those of the control agar fibers (2.4 GPa, 89.2 MPa, and 6.7 MJ m<sup>−3</sup>), overcoming the trade-off of stiffness-toughness for conventional nanocomposite systems. In addition, the agar/CNC nanocomposite fibers rapidly adsorbed Methylene blue within 90 min, which is significantly faster than that of the film-type agar adsorbent. Therefore, all-biomass-based agar/CNC fibers are a promising remedy for alleviating water pollution.</p></div>\",\"PeriodicalId\":683,\"journal\":{\"name\":\"Korea-Australia Rheology Journal\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2024-03-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Korea-Australia Rheology Journal\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s13367-024-00089-y\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MECHANICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Korea-Australia Rheology Journal","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s13367-024-00089-y","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MECHANICS","Score":null,"Total":0}
All-biomass-based strong nanocomposite fibers of agar and cellulose nanocrystals and their dye removal applications
Fiber-based commodities represent a substantial fraction of plastic waste, leading to environmental harm. Discarded sanitary masks and fishing equipment undergo degradation, generating microfiber plastics, thereby presenting a notable hazard to both human health and the ecosystem. In this study, mechanically strong and environmentally friendly nanocomposite fibers were prepared by dry-jet wet spinning. The all-biomass-based fibers comprised agar and cellulose nanocrystals (CNC) as the matrix and nanofiller, respectively, and were highly miscible in deionized water as a cosolvent. Based on rheological characterization, the optimal spinning concentration and temperature were set to 13% (w/v) and 95 °C, respectively. The dry-jet wet-spun agar-based fibers exhibited remarkable mechanical performance compared with previously reported agar-based materials. In particular, the 1 wt% CNC (with respect to the agar amount) simultaneously improved the Young’s modulus, strength, and toughness by 8.3, 4.8, and 16.4% (2.6 GPa, 93.5 MPa, and 7.8 MJ m−3), respectively, compared to those of the control agar fibers (2.4 GPa, 89.2 MPa, and 6.7 MJ m−3), overcoming the trade-off of stiffness-toughness for conventional nanocomposite systems. In addition, the agar/CNC nanocomposite fibers rapidly adsorbed Methylene blue within 90 min, which is significantly faster than that of the film-type agar adsorbent. Therefore, all-biomass-based agar/CNC fibers are a promising remedy for alleviating water pollution.
期刊介绍:
The Korea-Australia Rheology Journal is devoted to fundamental and applied research with immediate or potential value in rheology, covering the science of the deformation and flow of materials. Emphases are placed on experimental and numerical advances in the areas of complex fluids. The journal offers insight into characterization and understanding of technologically important materials with a wide range of practical applications.