用于高功率密度电机的新型高性能铜/石墨烯复合导体研究

Jiaxiao Wang;Tingting Zuo;Jiangli Xue;Yadong Ru;Yue Wu;Zhuang Xu;Yongsheng Liu;Zhaoshun Gao;Puqi Ning;Tao Fan;Xuhui Wen;Li Han;Liye Xiao
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引用次数: 0

摘要

以液态石蜡和铜铬合金粉为原料,通过热压烧结和剧烈冷塑性变形直接合成了纳米Cr3C2相协同强化的高性能铜/石墨烯复合材料线材。由于石墨烯是在烧结过程中在铜粉的催化作用下原位形成的,因此解决了石墨烯在铜基体中易团聚而难以均匀分散的问题。钉在界面上的纳米 Cr3C2 颗粒有利于改善界面结合。铜/石墨烯复合材料具有很高的导电性、硬度和可塑性。复合金属丝的导电率高达 96.93% IACS,抗拉强度高达 488 兆帕,并且具有优异的抗软化性能。即使在 400°C 退火 1 小时后,抗拉强度仍可达 268 兆帕,导电率约为 99.14% IACS。由于结构复杂,该金属丝的电阻温度系数(TCR)大大降低至 0.0035/°C,从而使其在较高温度下具有较低的电阻率。这种综合性能优异的铜/石墨烯复合导线在高功率密度电机中具有良好的应用前景。
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Investigation on the Novel High-performance Copper/Graphene Composite Conductor for High Power Density Motor
High-performance Cu/Graphene composite wire synergistically strengthened by nano Cr 3 C 2 phase was directly synthesized via hot press sintering followed by severe cold plastic deformation, using liquid paraffin and CuCr alloy powder as the raw materials. Since graphene is in situ formed under the catalysis of copper powder during the sintering process, the problem that graphene is easy to agglomerate and difficult to disperse uniformly in the copper matrix has been solved. The nano Cr 3 C 2 -particles nailed at the interface favor to improve the interface bonding. The Cu/Graphene composite possesses high electrical conductivity, hardness, and plasticity. The composite wire exhibits high electrical conductivity of 96.93% IACS, great tensile strength of 488 MPa, and excellent resistance to softening. Even after annealing at 400°C for 1 h, the tensile strength can still reach 268 MPa with a conductivity of about 99.14% IACS. The wire's temperature coefficient of resistance (TCR) is largely reduced to 0.0035/°C due to the complex structure, which leads the wire to present low resistivity at higher temperatures. Such Cu/Graphene composite wire with excellent comprehensive performance has a good application prospect in high-power density motors.
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