超级电容器应用中镍钴铁基复合材料合成策略综述

Yalda Tarpoudi Baheri, Amir Mahdi Homayounfard
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摘要

超级电容器(SC)以其超强的功率、合理的高能量密度、较长的使用寿命和较低的生产成本而著称,已成为满足各种储能应用日益增长的需求的理想解决方案。电极材料的选择在很大程度上影响着超级电容器的特性,因此开发新型电极材料成为高性能超级电容器领域广泛研究的焦点。近年来,由于镍钴氧化物具有理论容量高、成本低、供应充足、易于合成等显著优势,作为超级电容器电极材料受到越来越多的关注。然而,镍钴氧化物的低导电性和有限的表面积阻碍了其性能的发挥,导致容量显著下降。因此,有必要从多个角度系统、全面地总结在理解和调整基于镍钴氧化物的电极方面取得的进展。本综述主要关注生产具有不同形态的 NiCo2O4 纳米材料的合成方法,以便将其应用于超级电容器。本综述文章全面概述了用于开发超级电容器应用的镍钴基复合材料的合成方法。文章详细讨论了各种合成方法,包括溶胶-凝胶、水热和共沉淀技术,强调了优化合成参数对提高复合材料电化学性能的重要性。还探讨了镍钴铁基复合材料在超级电容器中的潜在应用,强调了其在储能技术中的广阔前景。此外,还讨论了该领域未来的研究方向。
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A review of synthesis strategies for nickel cobaltite-based composites in supercapacitor applications
Supercapacitors (SCs), known for their exceptional power and reasonably high energy densities, long lifespan, and lower production costs, have emerged as an ideal solution to meet the growing demand for various energy storage applications. The characteristics of supercapacitors are greatly influenced by means of the choice of electrode materials, developing novel electrode materials a focal point for extensive research in the field of high-performance supercapacitors. In recent years, NiCo2O4 has garnered increasing attention as a supercapacitor electrode material owing to its notable edges, including high theoretical capacity, low cost, abundant availability, and ease of synthesizing. However, the performance of NiCo2O4 is hindered by its low electrical conductivity and limited surface area, leading to significant capacity deterioration. Therefore, it is imperative to systematically and comprehensively summarize the advancements in comprehending and adjusting NiCo2O4-based electrodes from multiple perspectives. The present review primarily focuses on the synthetic approaches employed to produce NiCo2O4 nanomaterials with diverse morphologies for their application in supercapacitors. This review article provides a comprehensive overview of the synthesis approaches utilized for developing nickel cobaltite-based composites tailored for supercapacitor applications. Various synthesis methods, including sol-gel, hydrothermal, and co-precipitation techniques, are discussed in detail, emphasizing the importance of optimizing synthesis parameters to enhance the electrochemical performance of the composites. The potential applications of nickel cobaltite-based composites in supercapacitors are explored, highlighting their promising prospects in energy storage technologies. Future research directions in this field are also discussed.
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