受控钌催化的炔丙醇异构化反应

IF 1.7 4区化学 Q3 CHEMISTRY, ORGANIC Synlett Pub Date : 2024-04-02 DOI:10.1055/a-2288-3074

Steffen Skowaisa, Edgar Haak

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引用次数: 0

摘要

二氨基环戊二烯酮钌络合物可以通过选择添加剂来控制钌催化丙炔醇异构化反应的区域选择性。因此，迈耶-舒斯特重排产物和氧化还原异构化产物都可以选择性地获得。在羟胺-O-磺酸存在的情况下，则会形成不饱和腈。钌催化剂易于获得，并且对水分、空气和酸性条件稳定。

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Regiocontrolled Ruthenium-Catalyzed Isomerization of Propargyl Alcohols

A diaminocyclopentadienone ruthenium complex allows control of regioselectivity in the ruthenium-catalyzed isomerization of propargyl alcohols through the choice of additive. Thereby, both products of the Meyer–Schuster rearrangement and redox isomerization products are selectively accessible. In the presence of hydroxylamine-O-sulfonic acid, unsaturated nitriles are formed instead. The ruthenium catalyst is readily available and stable to moisture, air, and acidic conditions.

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来源期刊

Synlett 化学-有机化学

CiteScore

3.40

自引率

5.00%

发文量

369

审稿时长

1 months

期刊介绍： SYNLETT is an international journal reporting research results and current trends in chemical synthesis in short personalized reviews and preliminary communications. It covers all fields of scientific endeavor that involve organic synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines and offers the possibility to publish scientific primary data.