识别光辐射圆二色性的电子筛选长度

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-04-23 DOI:10.1016/j.elspec.2024.147439
Jiwon Jeon, J.D. Lee
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引用次数: 0

摘要

圆二色性角度分辨光发射光谱(CD-ARPES)因其对二维系统拓扑和量子几何性质的分辨能力而备受关注。我们提出了李普曼-施温格光电子终态,这是一种晶格模型的散射解,由周期性排列的原子位点上的屏蔽短程电势组成,它描述了时间反转的低能电子衍射(LEED)态,足以描述 CD-ARPES 中的终态效应。我们发现,通过终态效应,电子屏蔽长度不仅能确定 CD-ARPES 的定性分色极性,还能确定各种石墨烯体系(如单层石墨烯、AA 叠双层石墨烯和扭曲双层石墨烯)的定量分色强度,尤其是统一的分色强度。这一发现揭示了电子屏蔽和圆二色性之间的相互作用,并使 CD-ARPES 的光谱专业知识扩展到对电子屏蔽的直接探测。
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Electron screening length identifying circular dichroism of photoemission

Circular dichroism angle-resolved photoemission spectroscopy (CD-ARPES) receives much attention due to a resolving power of topological and quantum geometrical nature of two-dimensional systems. We propose the Lippmann-Schwinger photoelectron final state, a scattering solution of the lattice model comprising screened short-range potentials at periodically arranged atomic sites, which characterizes the time-reversed low energy electron diffraction (LEED) state well enough to describe the final state effect entailed in CD-ARPES. We find that, through the final state effect, the electron screening length identifies CD-ARPES not only in the qualitative dichroic polarity but also in the quantitative dichroic strength in various graphene systems like the monolayer graphene, the AA-stacking bilayer graphene, and the twisted bilayer graphene especially in a unified fashion. This finding reveals an interplay between electron screening and circular dichroism and enables to extend the spectroscopic expertise of CD-ARPES to a direct probe of the electron screening.

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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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