用氧化石墨烯增强椰壳活性炭去除采出水中的重金属

Samuel Ogidi, Mistura Yusuf, Khadijah Sanni, D. Andrea, Abdullahi Abdulsalam
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摘要

采出水含有大量碳氢化合物、重金属和其他污染物,是尼日尔三角洲油田和炼油厂的主要废物流之一。处理采出水的方法多种多样,包括物理方法(脱盐、膜分离和吸附)、化学方法(沉淀、吸收和氧化)和生物方法。废水中的重金属和污染物对生物和环境构成威胁。这项研究评估了用氧化石墨烯(研究人员从石墨中提取的一种新型茁壮成长的材料)改性的活性炭,利用 "湿浸渍技术 "提高椰子壳吸附能力的效果,以去除生产水中的重金属。对活性炭和改性活性炭(AC-GO)进行了污染物批量吸附研究,每种吸附剂的吸附时间都有一定的间隔。结果发现,随着接触时间的延长,吸附剂对镉、镍和铅的去除率分别从 6.71% 增加到 92.96%、3.01% 增加到 52.23%、51.28% 增加到 67.77%。原子吸收光谱(AAS)分析了经过处理的产水样品。对吸附金属的吸附等温线和动力学研究进行了评估,并与经验模型进行了关联。
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Removal of Heavy Metals from Produced Water Using Activated Carbon from Coconut Husk Enhanced with Graphene Oxide
Produced water, which contains a high amount of hydrocarbons, heavy metals, and other pollutants, is one of the major waste streams in the Niger Delta's oilfields and refineries. The treatment of produced water can be done in a variety of ways, including physical (desalination, membrane separation and, adsorption), chemical (precipitation, absorption and, oxidation), and biological. The heavy metals and contaminants in the wastewater pose a threat to living creatures and the environment. This research evaluates the effectiveness of Activated carbon modified with Graphene oxide, a new thriving material for researchers derived from graphite, to improve the adsorption capacity of coconut husk using the “wet impregnation technique” for the removal of heavy metals from produced water. Batch adsorption of the pollutant was studied for the Activated Carbon, and the modified activated carbon (AC-GO) at a time intervals, for each of the adsorbents. The removal efficiency of the adsorbent was found to increase proportionately from 6.71% to 92.96%, 3.01% to 52.23% and 51.28% to 67.77% for Cd, Ni and Pb respectively with increasing contact time. Atomic absorption spectroscopy (AAS) analysed the treated produced water samples. The adsorption isotherms and kinetics studies of the adsorbed metals were evaluated and correlated with empirical models.
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