Ljiljana Stojanović, Jack Coker, Samuele Giannini, Giacomo Londi, Anders S. Gertsen, Jens Wenzel Andreasen, Jun Yan, Gabriele D’Avino, David Beljonne, Jenny Nelson, Jochen Blumberger
{"title":"非富勒烯受体材料中从瞬态量子脱ocalization到电荷载流子跳变传导的无序诱导转变","authors":"Ljiljana Stojanović, Jack Coker, Samuele Giannini, Giacomo Londi, Anders S. Gertsen, Jens Wenzel Andreasen, Jun Yan, Gabriele D’Avino, David Beljonne, Jenny Nelson, Jochen Blumberger","doi":"10.1103/physrevx.14.021021","DOIUrl":null,"url":null,"abstract":"Nonfullerene acceptors have caused a step change in organic optoelectronics research but little is known about the mechanism and factors limiting charge transport in these molecular materials. Here a joint computational-experimental investigation is presented to understand the impact of various sources of disorder on the electron transport in the nonfullerene acceptor O-IDTBR. We find that in single crystals of this material, electron transport occurs in the transient quantum delocalization regime with the excess charge delocalized over about three molecules on average, according to quantum-classical nonadiabatic molecular-dynamics simulations. In this regime, carrier delocalization and charge mobility (<math display=\"inline\" xmlns=\"http://www.w3.org/1998/Math/MathML\"><mrow><msub><mrow><mi>μ</mi></mrow><mrow><mi>a</mi></mrow></msub><mo>=</mo><mn>7</mn><mtext> </mtext><mtext> </mtext><msup><mrow><mi>cm</mi></mrow><mrow><mn>2</mn></mrow></msup><mtext> </mtext><msup><mrow><mi mathvariant=\"normal\">V</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup><mtext> </mtext><msup><mrow><mi mathvariant=\"normal\">s</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup></mrow></math>) are limited by dynamical disorder of off-diagonal and diagonal electron-phonon coupling. In molecular assemblies representing disordered thin films, the additional static disorder of off-diagonal electron-phonon coupling is sufficient to fully localize the excess electron on single molecules, concomitant with a transition of transport mechanism from transient quantum delocalization to small polaron hopping and a drop in electron mobility by about 1 order of magnitude. Yet, inclusion of static diagonal disorder resulting from electrostatic interactions arising from the acceptor-donor-acceptor (A-D-A) structure of O-IDTBR, are found to have the most dramatic impact on carrier mobility, resulting in a further drop of electron mobility by about 4–5 orders of magnitude to <math display=\"inline\" xmlns=\"http://www.w3.org/1998/Math/MathML\"><msup><mn>10</mn><mrow><mo>−</mo><mn>5</mn></mrow></msup><mtext> </mtext><mtext> </mtext><msup><mrow><mi>cm</mi></mrow><mn>2</mn></msup><mtext> </mtext><msup><mi mathvariant=\"normal\">V</mi><mrow><mo>−</mo><mn>1</mn></mrow></msup><mtext> </mtext><msup><mi mathvariant=\"normal\">s</mi><mrow><mo>−</mo><mn>1</mn></mrow></msup></math>, in good agreement with thin-film electron mobility estimated from space-charge-limited-current measurements. Limitations due to diagonal disorder caused by electrostatic interactions are likely to apply to most nonfullerene acceptors. They imply that while A-D-A or A-DAD-A motifs are beneficial for photoabsorption and exciton transport, the electrostatic disorder they create can limit carrier transport in thin-film optoelectronic applications. This work shows the value of computational methods, in particular, nonadiabatic molecular-dynamics propagation of charge carriers, to distinguish different regimes of transport for different types of molecular packing.","PeriodicalId":20161,"journal":{"name":"Physical Review X","volume":null,"pages":null},"PeriodicalIF":11.6000,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Disorder-Induced Transition from Transient Quantum Delocalization to Charge Carrier Hopping Conduction in a Nonfullerene Acceptor Material\",\"authors\":\"Ljiljana Stojanović, Jack Coker, Samuele Giannini, Giacomo Londi, Anders S. 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In this regime, carrier delocalization and charge mobility (<math display=\\\"inline\\\" xmlns=\\\"http://www.w3.org/1998/Math/MathML\\\"><mrow><msub><mrow><mi>μ</mi></mrow><mrow><mi>a</mi></mrow></msub><mo>=</mo><mn>7</mn><mtext> </mtext><mtext> </mtext><msup><mrow><mi>cm</mi></mrow><mrow><mn>2</mn></mrow></msup><mtext> </mtext><msup><mrow><mi mathvariant=\\\"normal\\\">V</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup><mtext> </mtext><msup><mrow><mi mathvariant=\\\"normal\\\">s</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup></mrow></math>) are limited by dynamical disorder of off-diagonal and diagonal electron-phonon coupling. In molecular assemblies representing disordered thin films, the additional static disorder of off-diagonal electron-phonon coupling is sufficient to fully localize the excess electron on single molecules, concomitant with a transition of transport mechanism from transient quantum delocalization to small polaron hopping and a drop in electron mobility by about 1 order of magnitude. Yet, inclusion of static diagonal disorder resulting from electrostatic interactions arising from the acceptor-donor-acceptor (A-D-A) structure of O-IDTBR, are found to have the most dramatic impact on carrier mobility, resulting in a further drop of electron mobility by about 4–5 orders of magnitude to <math display=\\\"inline\\\" xmlns=\\\"http://www.w3.org/1998/Math/MathML\\\"><msup><mn>10</mn><mrow><mo>−</mo><mn>5</mn></mrow></msup><mtext> </mtext><mtext> </mtext><msup><mrow><mi>cm</mi></mrow><mn>2</mn></msup><mtext> </mtext><msup><mi mathvariant=\\\"normal\\\">V</mi><mrow><mo>−</mo><mn>1</mn></mrow></msup><mtext> </mtext><msup><mi mathvariant=\\\"normal\\\">s</mi><mrow><mo>−</mo><mn>1</mn></mrow></msup></math>, in good agreement with thin-film electron mobility estimated from space-charge-limited-current measurements. Limitations due to diagonal disorder caused by electrostatic interactions are likely to apply to most nonfullerene acceptors. They imply that while A-D-A or A-DAD-A motifs are beneficial for photoabsorption and exciton transport, the electrostatic disorder they create can limit carrier transport in thin-film optoelectronic applications. This work shows the value of computational methods, in particular, nonadiabatic molecular-dynamics propagation of charge carriers, to distinguish different regimes of transport for different types of molecular packing.\",\"PeriodicalId\":20161,\"journal\":{\"name\":\"Physical Review X\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":11.6000,\"publicationDate\":\"2024-04-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Physical Review X\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.1103/physrevx.14.021021\",\"RegionNum\":1,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"PHYSICS, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physical Review X","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1103/physrevx.14.021021","RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"PHYSICS, MULTIDISCIPLINARY","Score":null,"Total":0}
Disorder-Induced Transition from Transient Quantum Delocalization to Charge Carrier Hopping Conduction in a Nonfullerene Acceptor Material
Nonfullerene acceptors have caused a step change in organic optoelectronics research but little is known about the mechanism and factors limiting charge transport in these molecular materials. Here a joint computational-experimental investigation is presented to understand the impact of various sources of disorder on the electron transport in the nonfullerene acceptor O-IDTBR. We find that in single crystals of this material, electron transport occurs in the transient quantum delocalization regime with the excess charge delocalized over about three molecules on average, according to quantum-classical nonadiabatic molecular-dynamics simulations. In this regime, carrier delocalization and charge mobility () are limited by dynamical disorder of off-diagonal and diagonal electron-phonon coupling. In molecular assemblies representing disordered thin films, the additional static disorder of off-diagonal electron-phonon coupling is sufficient to fully localize the excess electron on single molecules, concomitant with a transition of transport mechanism from transient quantum delocalization to small polaron hopping and a drop in electron mobility by about 1 order of magnitude. Yet, inclusion of static diagonal disorder resulting from electrostatic interactions arising from the acceptor-donor-acceptor (A-D-A) structure of O-IDTBR, are found to have the most dramatic impact on carrier mobility, resulting in a further drop of electron mobility by about 4–5 orders of magnitude to , in good agreement with thin-film electron mobility estimated from space-charge-limited-current measurements. Limitations due to diagonal disorder caused by electrostatic interactions are likely to apply to most nonfullerene acceptors. They imply that while A-D-A or A-DAD-A motifs are beneficial for photoabsorption and exciton transport, the electrostatic disorder they create can limit carrier transport in thin-film optoelectronic applications. This work shows the value of computational methods, in particular, nonadiabatic molecular-dynamics propagation of charge carriers, to distinguish different regimes of transport for different types of molecular packing.
期刊介绍:
Physical Review X (PRX) stands as an exclusively online, fully open-access journal, emphasizing innovation, quality, and enduring impact in the scientific content it disseminates. Devoted to showcasing a curated selection of papers from pure, applied, and interdisciplinary physics, PRX aims to feature work with the potential to shape current and future research while leaving a lasting and profound impact in their respective fields. Encompassing the entire spectrum of physics subject areas, PRX places a special focus on groundbreaking interdisciplinary research with broad-reaching influence.