用于高性能超级电容器的星形 PEDOT:PSS 导电聚合物与还原氧化石墨烯

IF 2.8 4区 工程技术 Q2 POLYMER SCIENCE Macromolecular Research Pub Date : 2024-05-10 DOI:10.1007/s13233-024-00267-5
Long Shen, Yunhee Ahn, Yoon Kim, Suyeon Kim, Sunghee Choi, Tae-Dong Kim, Dongju Lee
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引用次数: 0

摘要

通过原子转移自由基聚合(ATRP)合成了三臂聚(苯乙烯磺酸)衍生物(PSS-T),并将其作为掺杂剂用于制备星形 PEDOT:PSS-T 复合材料。还原氧化石墨烯(rGO)从其松散的堆积结构出发,被很好地掺杂到 PEDOT:PSS-T 复合材料中,从而改善了其分散性能并提高了电性能。使用 PEDOT:PSS-T/rGO 复合材料制成的超级电容器在经过 10,000 次充放电循环后,其电容保持率达到 95.5%,优于使用商用 PEDOT:PSS/rGO 复合材料制成的装置。图文摘要星形 PEDOT:PSS-T 复合材料的结构及其优异的电容稳定性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Star-shaped PEDOT:PSS conductive polymers with reduced graphene oxide for high performance supercapacitor

Three-armed poly(styrene sulfonate) derivatives (PSS-T) was synthesized by atom transfer radical polymerization (ATRP) and used as dopants for the preparation of star-shaped PEDOT:PSS-T composites. From their loosed packing structure, reduced graphene oxide (rGO) was well doped into the PEDOT:PSS-T composites resulted in improved dispersion properties and enhanced electrical performance. The cyclic stability of supercapacitors using PEDOT:PSS-T/rGO composites showed 95.5% capacitance retention after 10,000 charge/discharge cycles which is superior than its devices using of commercial PEDOT:PSS/rGO composites.

Graphical abstract

The structure of star-shaped PEDOT:PSS-T composite and its excellent capacitance stability.

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来源期刊
Macromolecular Research
Macromolecular Research 工程技术-高分子科学
CiteScore
4.70
自引率
8.30%
发文量
100
审稿时长
1.3 months
期刊介绍: Original research on all aspects of polymer science, engineering and technology, including nanotechnology Presents original research articles on all aspects of polymer science, engineering and technology Coverage extends to such topics as nanotechnology, biotechnology and information technology The English-language journal of the Polymer Society of Korea Macromolecular Research is a scientific journal published monthly by the Polymer Society of Korea. Macromolecular Research publishes original researches on all aspects of polymer science, engineering, and technology as well as new emerging technologies using polymeric materials including nanotechnology, biotechnology, and information technology in forms of Articles, Communications, Notes, Reviews, and Feature articles.
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