掺杂铒(III)的氟锆酸磷酸盐玻璃和玻璃陶瓷:可见光和近红外发光

IF 0.8 4区 化学 Q4 SPECTROSCOPY Journal of Applied Spectroscopy Pub Date : 2024-05-08 DOI:10.1007/s10812-024-01717-9
I. G. Maslennikova, V. K. Goncharuk, A. G. Mirochnik, A. A. Sergeev
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引用次数: 0

摘要

比较了掺杂铒(III)的氟锆酸盐玻璃和氟锆酸盐磷酸盐玻璃以及含有 NaPO3 的玻璃陶瓷的发光特性。这些玻璃是通过快速熔融淬火获得的,并使用发光光谱、差热分析、X 射线衍射和透射电子显微镜对其进行了表征。加入 NaPO3 后,Er(III) 在近红外(NIR)区域的相对发光强度在 1530 纳米处增加了一倍(4I13/2 → 4I15/2 转变)。可见光和近红外区域其他波段的发光强度则有所下降。对所研究样品的发光量子产率和寿命进行了测量。讨论了添加 NaPO3 和热处理样品后发光强度发生变化的原因。
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Erbium(III)-Doped Fluorozirconate Phosphate Glasses and Glass Ceramics: Visible and NIR Luminescence

The luminescent properties of erbium(III)-doped fluorozirconate glass and fluorozirconate phosphate glass and glass ceramics containing NaPO3 were compared. The glasses were obtained by rapid melt quenching and were characterized using luminescence spectroscopy, differential thermal analysis, x-ray diffraction, and transmission electron microscopy. When NaPO3 was added, the relative luminescence intensity of Er(III) in the near infrared (NIR) region doubled at 1530 nm (4I13/24I15/2 transition). The luminescence intensity of other bands in the visible and NIR regions decreased. Luminescence quantum yields and lifetimes of the studied samples were measured. The reasons for the change in luminescence intensity after addition of NaPO3 and heat treatment of the samples were discussed.

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来源期刊
CiteScore
1.30
自引率
14.30%
发文量
145
审稿时长
2.5 months
期刊介绍: Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.
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