I. G. Maslennikova, V. K. Goncharuk, A. G. Mirochnik, A. A. Sergeev
{"title":"掺杂铒(III)的氟锆酸磷酸盐玻璃和玻璃陶瓷:可见光和近红外发光","authors":"I. G. Maslennikova, V. K. Goncharuk, A. G. Mirochnik, A. A. Sergeev","doi":"10.1007/s10812-024-01717-9","DOIUrl":null,"url":null,"abstract":"<p>The luminescent properties of erbium(III)-doped fluorozirconate glass and fluorozirconate phosphate glass and glass ceramics containing NaPO<sub>3</sub> were compared. The glasses were obtained by rapid melt quenching and were characterized using luminescence spectroscopy, differential thermal analysis, x-ray diffraction, and transmission electron microscopy. When NaPO<sub>3</sub> was added, the relative luminescence intensity of Er(III) in the near infrared (NIR) region doubled at 1530 nm (<sup>4</sup>I<sub>13/2</sub> → <sup>4</sup>I<sub>15/2</sub> transition). The luminescence intensity of other bands in the visible and NIR regions decreased. Luminescence quantum yields and lifetimes of the studied samples were measured. The reasons for the change in luminescence intensity after addition of NaPO<sub>3</sub> and heat treatment of the samples were discussed.</p>","PeriodicalId":609,"journal":{"name":"Journal of Applied Spectroscopy","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Erbium(III)-Doped Fluorozirconate Phosphate Glasses and Glass Ceramics: Visible and NIR Luminescence\",\"authors\":\"I. G. Maslennikova, V. K. Goncharuk, A. G. Mirochnik, A. A. Sergeev\",\"doi\":\"10.1007/s10812-024-01717-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The luminescent properties of erbium(III)-doped fluorozirconate glass and fluorozirconate phosphate glass and glass ceramics containing NaPO<sub>3</sub> were compared. The glasses were obtained by rapid melt quenching and were characterized using luminescence spectroscopy, differential thermal analysis, x-ray diffraction, and transmission electron microscopy. When NaPO<sub>3</sub> was added, the relative luminescence intensity of Er(III) in the near infrared (NIR) region doubled at 1530 nm (<sup>4</sup>I<sub>13/2</sub> → <sup>4</sup>I<sub>15/2</sub> transition). The luminescence intensity of other bands in the visible and NIR regions decreased. Luminescence quantum yields and lifetimes of the studied samples were measured. The reasons for the change in luminescence intensity after addition of NaPO<sub>3</sub> and heat treatment of the samples were discussed.</p>\",\"PeriodicalId\":609,\"journal\":{\"name\":\"Journal of Applied Spectroscopy\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2024-05-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Spectroscopy\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10812-024-01717-9\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"SPECTROSCOPY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10812-024-01717-9","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"SPECTROSCOPY","Score":null,"Total":0}
Erbium(III)-Doped Fluorozirconate Phosphate Glasses and Glass Ceramics: Visible and NIR Luminescence
The luminescent properties of erbium(III)-doped fluorozirconate glass and fluorozirconate phosphate glass and glass ceramics containing NaPO3 were compared. The glasses were obtained by rapid melt quenching and were characterized using luminescence spectroscopy, differential thermal analysis, x-ray diffraction, and transmission electron microscopy. When NaPO3 was added, the relative luminescence intensity of Er(III) in the near infrared (NIR) region doubled at 1530 nm (4I13/2 → 4I15/2 transition). The luminescence intensity of other bands in the visible and NIR regions decreased. Luminescence quantum yields and lifetimes of the studied samples were measured. The reasons for the change in luminescence intensity after addition of NaPO3 and heat treatment of the samples were discussed.
期刊介绍:
Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.