通过不同工业干燥工艺获得的含有阳极氧化铝废料的摩擦材料的摩擦学特性

G. Straffelini, P. Jayashree, Andrea Barbieri, Roberto Masciocchi
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摘要

随着可持续发展在工业中占据主导地位,回收利用不同工艺产生的废料变得越来越重要。本研究的重点是在汽车制动应用的摩擦材料配方中回收阳极氧化铝废料(AAW)过程中产生的废料。然而,在利用之前,需要对废料进行预处理,主要包括干燥。因此,我们研究了四种不同的工业干燥方法来干燥 AAW,并通过评估其残余湿度和压碎指数来观察其相应特性。利用傅立叶变换红外光谱和扫描电镜/可见分光光度计对废粉进行了进一步表征,以了解其成分。初步分析表明,采用最终湿度最低的 P2 和 P1 干燥工艺的废料得到了最理想的结果,其中 P1 的干燥工艺更简单。在商用摩擦材料配方中添加了重量百分比为 6% 和 12% 的 AAW 粉末,并对其进行了摩擦、磨损和非排气颗粒物分析。使用 SEM/EDXS 评估对磨损表面进行了分析,以了解沉积的二次接触层的扩展和成分。结果表明,采用 P1 技术处理的 12 wt.%添加量的废料具有最令人满意的摩擦、磨损和排放特性,同时二次接触层具有扩展性,废料在其形成过程中起到了很好的作用。这项研究表明,加工方法与配方的摩擦学和排放特性之间存在良好的关系,从而为将这种干燥方法用于其他需要预处理的废物铺平了道路。
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Tribological Behavior of Friction Materials Containing Aluminum Anodizing Waste Obtained by Different Industrial Drying Processes
With sustainability dominating the industry, recycling the generated waste from different processes is becoming increasingly important. This study focuses on recycling waste generated during aluminum anodizing waste (AAW) in friction material formulations for automotive braking applications. However, before utilization, the waste needs to be pre-treated, which mainly involves drying. Hence, four different industrial drying methods were studied to dry the AAW, and the corresponding characteristics were observed by evaluating its residual humidity and crushability index. The waste powders were further characterized using FT-IR and SEM/EDXS to understand their constituents. The initial analysis showed that the waste subjected to the drying process P2 and P1 with the lowest final humidity fetched the most desirable results, with P1 having the simpler drying procedure. The AAW powders were added in a commercial friction material formulation at 6 and 12 wt.% and subjected to friction, wear, and non-exhaust particulate matter analysis. The worn surfaces were analyzed using SEM/EDXS evaluation to understand the extension and composition of the deposited secondary contact plateaus. It was seen that the 12 wt.% addition of waste processed using the P1 technique provided the most satisfactory friction, wear, and emission characteristics, along with expansive secondary contact plateaus with a good contribution of the waste in its formation. This study showed a good relationship between the processing method and a formulation’s tribological and emission characteristics, thereby paving the way for using this drying method for other waste requiring pre-treatment.
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