利用舍勒方程确定二氧化钛/EG-水 XRD 数据的晶粒尺寸

Muhamad Taufik Ulhakim, S. Sukarman, Khoirudin Khoirudin, Nazar Fazrin, Tomas Irfani, Afif Hakim
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引用次数: 0

摘要

利用 X 射线衍射 (XRD) 数据和舍勒方程分析了二氧化钛 (TiO2) 在乙二醇 (EG) 和蒸馏水溶液中的晶粒大小。XRD 分析使用的是 Rigaku Miniflex 600 仪器,X 射线波长约为 0.15046 纳米。检查得出了全宽半最大值 (FWHM),随后使用舍勒方程对其进行了检验。该实验使用的二氧化钛纯度为 99.8%,晶体尺寸为 30 纳米。分析表明,样品中二氧化钛的平均晶粒大小为 19.45 纳米,最高测量值约为 30.38 纳米。采用斯皮尔曼相关方程来验证结果。FWHM 变量与 TiO2 纳米粒子晶粒大小之间的斯皮尔曼相关系数为-0.958。这些发现揭示了 TiO2 在这些条件下的晶体结构。这些发现为 TiO2 在各种纳米技术中的应用提供了支持。然而,还需要进行更多的研究,以充分了解晶体大小的 TiO2 纳米粒子在不同环境下的工作原理,并找到制备样品的最佳方法,包括了解特定相以及它如何影响流体的稳定性。这项研究对了解 TiO2 在蒸馏水和 EG 溶液中的特性以及纳米材料的表征做出了重要贡献,尤其是对可持续发展目标中有关工业、创新和基础设施的第 9 项目标具有重要意义。
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Determining The Crystallite Size of TiO2/EG-Water XRD Data Using the Scherrer Equation
X-ray diffraction (XRD) data and the Scherrer equation were utilized to analyze the crystallite Size of titanium dioxide (TiO2) in a solution of ethylene glycol (EG) and distilled water. The XRD analysis was conducted using a Rigaku Miniflex 600 instrument with an X-ray wavelength of approximately 0.15046 nm. The examination yielded the full-width half maximum (FWHM), which was subsequently examined using the Scherrer equation. This experiment employed TiO2 with a purity level of 99.8% and a crystal Size of 30 nm. The analysis revealed that the average crystallite Size of TiO2 in the sample is 19.45 nm, with the highest measurement at about 30.38 nm. The Spearman correlation equation was employed to validate the outcomes. The Spearman's correlation coefficient between the FWHM variable and the crystallite Size of TiO2 nanoparticles is -0.958. These findings shed light on the crystal structure of TiO2 under these conditions. These findings lend support to the use of TiO2 in a variety of nanotechnology applications. However, more research is needed to understand fully how crystallite-Size TiO2 nanoparticles work in different settings and to find the best ways to prepare samples, including understanding the specific phase and how it affects the stability of fluids. This research contributes significantly to the understanding of the properties of TiO2 in a solution of distilled water and EG, as well as to the characterization of nanomaterials, with particular emphasis on issue 9 of the SDGS Goal concerning industry, innovation, and infrastructure.
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